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µÚ¶þÕ ±¥ºÍÌþÏ°Ìâ(P60)

(Ò») ÓÃϵͳÃüÃû·¨ÃüÃûÏÂÁи÷»¯ºÏÎ²¢Ö¸³öÕâЩ»¯ºÏÎïÖеIJ®¡¢ÖÙ¡¢Êå¡¢¼¾Ì¼Ô­×Ó¡£

(1) 1234567

3-¼×»ù-3-ÒÒ»ù¸ýÍé

21(3)

43

652,5-¶þ¼×»ù-3,4-¶þÒÒ»ù¼ºÍé

(5) ÒÒ»ù»·±ûÍé

109123(7)

87654 1,7-¶þ¼×»ù-4-Òì±û»ùË«»·[4.4.0]¹ïÍé

145(9)

36 275-Ò춡»ùÂÝ[2.4]¸ýÍé

(11)

HC

32-¼×»ù»·±û»ù

(2) 21345

2,3-¶þ¼×»ù-3-ÒÒ»ùÎìÍé

86975(4) 10124

31,1-¶þ¼×»ù-4-Òì±û»ù»·¹ïÍé

1(6)

42 32-»·±û»ù¶¡Íé

6541(8) 72CH3

8932-¼×»ùÂÝ[3.5]ÈÉÍé

(10) (CH3)3CCH2

ÐÂÎì»ù

(12)

CH3CH2CH2CH2CHCH3

2-¼º»ù or (1-¼×»ù)Îì»ù

(¶þ) д³öÏ൱ÓÚÏÂÁÐÃû³ÆµÄ¸÷»¯ºÏÎïµÄ¹¹Ôìʽ£¬ÈçÆäÃû³ÆÓëϵͳÃüÃûÔ­Ôò²»·û£¬ÓèÒÔ¸ÄÕý¡£

(1) 2,3-¶þ¼×»ù-2-ÒÒ»ù¶¡Íé

(2) 1,5,5-Èý¼×»ù-3-ÒÒ»ù¼ºÍé

(3) 2-Ê嶡»ù-4,5-¶þ¼×»ù¼ºÍé

CH3CH3CH3CCHCH3CH3CH2CH2CHCH2C2H5

(5) ¶¡»ù»·±ûÍé

CH3CCH3CH3C(CH3)3CH3CH3CH3CCH2CHCHCH3CH2CH32,3,3-Èý¼×»ùÎìÍé

(4) ¼×»ùÒÒ»ùÒì±û»ù¼×Íé

2,2-¶þ¼×»ù-4-ÒÒ»ù¸ýÍé 2,2,3,5,6-Îå¼×»ù¸ýÍé

(6) 1-¶¡»ù-3-¼×»ù»·¼ºÍé

CH3CH3CH3CH2CHCHCH3CH2CH2CH2CH3CH2CH2CH2CH3CH32,3-¶þ¼×»ùÎìÍé 1-»·±û»ù¶¡Íé 1-¼×»ù-3-¶¡»ù»·¼ºÍé

(Èý) ÒÔC2ÓëC3µÄ¦Ò¼üΪÐýתÖᣬÊԷֱ𻭳ö2,3-¶þ¼×»ù¶¡ÍéºÍ2,2,3,3-Ëļ׻ù¶¡ÍéµÄµäÐ͹¹Ïóʽ£¬²¢Ö¸³öÄÄÒ»¸öΪÆä×îÎȶ¨µÄ¹¹Ïóʽ¡£

½â£º2,3-¶þ¼×»ù¶¡ÍéµÄµäÐ͹¹Ïóʽ¹²ÓÐËÄÖÖ£º

CH3CH3HCH3( I )(×îÎȶ¨¹¹Ïó)HCH3CH3HHCH3HCH3CH3CH3( III )

HCH3H3CCH3( II )CH3CH3H3CCH3HHCH3CH3CH3CH3( III )HHH3CCH3HCH3( II )CH3CH3H3CCH3( II )HCH3( IV )(×î²»Îȶ¨¹¹Ïó)CH3H3CH3CCH3CH3CH3( I )(×îÎȶ¨¹¹Ïó)2,2,3,3-Ëļ׻ù¶¡ÍéµÄµäÐ͹¹Ïóʽ¹²ÓÐÁ½ÖÖ£º

CH3CH3

(ËÄ) ½«ÏÂÁеÄͶӰʽ¸ÄΪ͸ÊÓʽ£¬Í¸ÊÓʽ¸ÄΪͶӰʽ¡£

Cl(1)

CH3H

Cl H3CHCH3

HCH3CH3(2)

ClCH3HClCH3H

HCH3ClHCl

HClCH3CH3ClClCl

HC3H3CClHHCl

(3)

HHCH3(4)

H3CCH3

CH3HBrHBrHH

BrBrCH3Br(5)

HH

CH3Br

HBrCH3BrCH3H(Îå) ÓÃ͸ÊÓʽ¿ÉÒÔ»­³öÈýÖÖCH3-CFCl2µÄ½»²æʽ¹¹Ïó£º

HFHHClHHHClHHHClClFClClF

ËüÃÇÊDz»ÊÇCH3-CFCl2µÄÈýÖÖ²»Í¬µÄ¹¹Ïóʽ£¿ÓÃNewmanͶӰʽ±íʾ²¢ÑéÖ¤ËùµÃ½áÂÛÊÇ·ñÕýÈ·¡£

½â£ºËüÃÇÊÇCH3-CFCl2µÄͬһÖÖ¹¹Ï󡪡ª½»²æʽ¹¹Ïó!

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FHClH(I)HClHClClHFH(II)HFClHClH(II)