【最新】徐寿昌主编《有机化学?第二?-课后1-13章习题答?- 百度文库

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CH3A:BrB:BrCH3CH2BrC:CH3

CH3CH2BrBrD:CH3CH2

CH3BrBr+CH3+BrHBrCH3BrCH2CH3Br+CH3KOC(CH3)3CH2CH2CH2O3OZn,H2O2HCHO+OCC

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ھ ±

1л

CH2Cl2CH2CH2CH2ClClCH2=CCHCH=CHCH2BrCH3

14ȶ 2׻3ȣ6壭14ϩ

CH2CH3CH3CHBrCHCHCH3

2ȣ3ϩ 2׻3һ4

BrClClClCH3

4屽 3Ȼϩ

F2C=CF2CH3Br

ķϩ 4׻1廷ϩ 2длĽṹʽ

1ϩ 2

CH2=CHCH2Cl

34׻5ȣ2Ȳ 4һ廷

CH2Br

CH3CCCHCH2Cl

Br

CH3CH2CH2BrCL2C=CH2CCl2F2HCCl3

3зӦʽ

(1)CH3CH=CH2+HBrCH3CHCH3NaCNCH3CHCH3BrCN

ROOR+CHCH=CHHBr(2)32H2O(KOH)CH3CH2CH2OHCH3CH2CH2Br

(3)CH3CH=CH2+Cl20500CClCH2CH=CH2Cl2+H2OClCHCHCHCl22OH

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Cl(4)

+Cl2Cl2KOH

(5)NBSBrKICH3COCH3I

CH3(6)CH3CHCHCH3CH3OH(7)(CH3)3CBr+KCN

PCl5CH3CHCHCH3NH3CH3ClCH2=C(CH3)2

CH3CHCHCH3NH2

C2H5OH(8)CH3CHCH3OHPBr5CH3CHCH3BrAgNO3/C2H5OHCH3CHCH3ONO2

(9)C2H5MgBr+CH3CH2CH2CH2CCHCH3CH3+CH3CH2CH2CH2CCMgBr

CH3COOHClCH=CHCH2OOCCH3+NaCl(10)ClCH=CHCH2Cl+CH3COONa

(11)CHCH+2Cl2Cl2CHCHCl2KOH(C2H5OH)(1mol)ClC=CClHCl

NaCNNH3+CH2CNCH2NH2CH2OC2H5CH2ICH2Cl(12)C2H5ONaNaI/CH3COCH3H2O,-OHCH2OH

4÷ʽʾCH3CH2CH2CH2BrлﷴӦҪ

1 CH3CH2CH2CH2OH 3 CH3CH2CH2CH2MgBrCH3CH2CH2CH3,HCCMg2 CH3CH2CH=CH2 4 CH3CH2CH2CH2I

6 CH3CH2CH2CH2CN

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5 CH3CH2CH2CH2NH2

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7 CH3CH2CH2CH2ONO2

9 CH3CH2CH2CH2CH2CH2CH2CH3 5ûѧл: ⣺1 Br2,aq Һ 2 CH3CH=CHCl ɫ CH2=CHCH2Cl ɫ Ȼ ȴ ȱ CH3CH2CH2Cl 8 CH3CCCH2CH2CH2CH3

10 CH3CH2CH2CH2N(CH3)2

Һ ȻȻҲӦ 3 1 2嶡 1 Һ ɰɫȻɵɫ ɫ⻯ 4 ȱ 21 Һ Ӧ Ȼ ȲȻ 6и黯ﰴӦٶȴС˳У ⣺1SN1Ӧ

CH3

(a)(CH3)3CBr,>CH3CH2CHBr>CH3CH2CH2CH2Br,

(b)CHCH3BrCH2Br>>CH2CH2Br

2SN2Ӧ

(a)CH3CH2CH2Br>(CH3)2CHCH2Br>(CH3)3CCH2Br

(CH3)3CBr

CH3(b)CH3CH2CH2CH2Br>CH3CH2CHBr>7и黯ﰴȥ廯״УдĹʽ ⣺1

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