娌冲崡鍐滀笟澶у
2013-2014
瀛﹀勾绗竴瀛︽湡鏈熺粓鑰冭瘯
鍒嗘瀽鍖栧璇曢锛?/p>
A
锛夌瓟妗堝強璇勫垎鏍囧噯
閫傜敤鐝骇锛氬簲鍖?/p>
12-1,2
銆佸寲鐢?/p>
12-1,2
涓�銆侀�夋嫨棰?/p>
(
鏈鍙湁
15
灏忛锛屾瘡灏忛鍙湁涓�涓纭瓟妗堬紝鍒嗗�间负
2
鍒嗭紝鎬昏
30
鍒?/p>
)
1
锛?/p>
C
A
B
B
C;
6
锛?/p>
B
A
A
C
D;
11
锛?/p>
B
C
D
D
A
浜屻�佸～绌洪锛?/p>
锛堝寘鎷?/p>
10
灏忛锛屾瘡灏忛
2
鍒嗭紝鍏?/p>
20
鍒嗭級
1
锛?/p>
Na
2
CO
3
銆?/p>
NaHCO
3
2
锛?/p>
飥?/p>
飥?/p>
飥?/p>
飥?/p>
A
g
C
l
A
g
B
r
sp
sp
K
K
飥?/p>
3
锛?/p>
[L]
4
锛?/p>
2[H
3
PO
4
]+[H
2
PO
4
-
]+[H
3
O
+
]=[NH
3
]+[PO
4
3-
]+[OH
-
]
5
锛?/p>
_6__
6
锛?/p>
_3___
7
锛?/p>
__
绉绘恫绠?/p>
__
__
閲忕瓛
__ 8
锛?/p>
___
閭昏嫰浜岀敳閰告阿閽?/p>
__ 9
锛?/p>
_0.32V___
10
锛?/p>
鍚告敹鏈�澶э紝骞叉壈鏈�灏?/p>
涓夈�佺畝绛旈锛堟湰棰樺叡鏈変袱灏忛锛屾瘡灏忛
5
鍒嗭紝璁?/p>
10
鍒嗭級
1
锛庣瓟锛氭爣瀹?/p>
Na
2
S
2
O
3
鏍囧噯婧舵恫甯哥敤鏂规硶鎵�闇�鐨勪富瑕佽瘯鍓傛湁锛?/p>
K
2
Cr
2
O
7
銆?/p>
KI
銆佸彲婧舵�ф穩绮夈�?/p>
3
鍒?/p>
鍙嶅簲鏂圭▼寮忎负锛?/p>
Cr
2
O
7
2-
+6I
-
+14H
+
=2Cr
3+
+3I
2
+7H
2
O
1
鍒?/p>
I
2
+2S
2
O
3
2
锛?
=2I
锛?
+S
4
O
6
2
锛?
1
鍒?/p>
2
銆侀吀纰辨寚绀哄墏鍙樿壊鏄殢鐫�閰稿害鐨勫彉鍖栵紝鎸囩ず鍓傜粨鍚堟垨绂昏В鍑?/p>
H
+
锛岀粨鏋勫彂鐢熷彉鍖栵紝浠庤�屽彂鐢熼
鑹叉敼鍙?/p>
(1
鍒?/p>
)
锛?/p>
缁滃悎鎸囩ず鍓備笌閲戝睘绂诲瓙缁滃悎鍓嶅悗棰滆壊涓嶅悓锛?/p>
娓哥鐨勮瘯鍓備负涓�绉嶉鑹诧紝
涓庨噾灞炵瀛?/p>
褰㈡垚缁滃悎鐗╁張涓�绉嶉鑹?/p>
(1
鍒?/p>
)
锛?/p>
姘у寲杩樺師鎸囩ず鍓傚彉鑹插垎涓哄嚑绉嶆儏鍐碉細
涓�绉嶆槸闅忔哀鍖栬繕鍘熺數浣嶅彉鍖?/p>
鐨勮瘯鍓傦紝鍦ㄦ哀鍖栨�佸拰杩樺師鎬侊紝缁撴瀯涓嶅悓锛屽悇鏈変笉鍚岄鑹诧紝濡備簩鑻兒纾洪吀閽狅紝杩樺師鎬佹棤鑹诧紝姘у寲
鎬佺传绾㈣壊
(1
鍒?/p>
)
锛涘彟涓�绉嶈嚜韬寚绀哄墏锛屽楂橀敯閰搁捑
(1
鍒?/p>
)
锛涜繕鏈夋樉鑹叉寚绀哄墏濡?/p>
I
2
锛屼笌娣�绮夋樉鍏拌壊
(1
鍒?/p>
)
銆?/p>
鍥涖�佽绠楅锛堟湰棰樺叡鏈?/p>
4
灏忛锛屾瘡棰樹负
10
鍒嗭紝璁?/p>
40
鍒嗭級
1
锛?/p>
瑙?/p>
:
鈭?/p>
K
sp
杈冨ぇ
,
鍋囪
S
2-
瀹氶噺鎴愪负
HS
-
,
浜х敓鍚岄噺
OH
-
1
鍒?/p>
鈭村亣璁?/p>
MnS+H
2
O=Mn
2+
+HS
锛?
+OH
锛?
1
鍒?/p>
S
S
S
1
鍒?/p>
2
鍒?/p>
2
鍒?/p>
2+
2-
s
+
-
2+
-
2
w
p
-
a
a2
-12.6-14.0
-13.7
-12.9
[H
][OH
]
=
[Mn
][HS
][OH
]
=
10
=
=
=
10
10
[Mn
][S
]
K
K
K
K
K
飦?/p>
-1
-13.7/3
- 4.6
3
=
=
10
=
10
mol
L
S
K
飦?/p>