鍥轰綋閿傜瀛愮數姹犵敤鐢佃В璐ㄨВ鍐虫柟妗?/p>
13
Li3N
绯诲垪閿傞櫠鐡风數瑙ｈ川
Li3N
鏄敱寰峰浗
鐨勪竴瀹?/p>
鐮旂┒鎵�鍙戠幇鐨勪竴绉嶅娓╃數瀵肩巼杈冮珮涓斿閲?/p>
灞為攤绋冲畾鐨勯攤蹇瀛愬浣?/p>
,
鍏舵櫠浣撶粨鏋勫睘鍏柟鏅剁郴锛屽湪鍨傜洿浜?/p>
C
杞存柟
鍚戝寘鍚袱灞傦細涓�灞傛槸
Li2N
锛屽彟涓�灞傛槸绾?/p>
Li
灞傘�傚眰鐘剁殑
Li3N
鏄簩缁寸瀛?/p>
瀵间綋锛屽湪鍨傜洿浜?/p>
C
杞存柟鍚戠殑瀹ゆ俯鐢靛鐜囪揪
10
-3
S/cm
锛岃�屽钩琛屼簬
C
杞存柟鍚?/p>
鐨勭瀛愮數瀵肩巼鍗村緢浣庛�?/p>
瀹為檯鐨?/p>
Li3N
鏅朵綋骞朵笉瀹屽叏绗﹀悎鍖栧璁￠噺寮忥紝
鍦?/p>
鍏?/p>
Li2N
灞備腑澶х害鏈?/p>
1%
锝?/p>
2%
鐨勯攤绌轰綅锛岃繖浜涘皯閲忕殑绌轰綅瀵?/p>
Li3N
鐨?/p>
Li
+
瀵?/p>
鐢垫�у叿鏈夐噸瑕佺殑鎰忎箟銆傜爺绌惰〃鏄庯紝
Li2N
灞備腑鐨?/p>
Li
+
鐢熸垚鑷敱鑳戒綆锛屽崌
楂樻俯搴﹀彲澶у箙搴﹀鍔犻攤绌轰綅鏁扮洰锛屽彈鐑縺鍙戠殑
Li
+
鎵�浣滅殑绠�璋愭尟鍔ㄤ互
Li2N
灞傚唴鎸姩涓轰富锛屼粠鑰屽舰鎴愪竴涓簩缁村鐢电綉缁滐紱绾攤灞備腑鐨?/p>
Li
+
铏?/p>
鐒舵帓鍒楀畬鍏ㄦ湁搴忥紝浣嗗墿浣欑┖闂村ぇ锛屽悓鏍峰彲浠ュ弬涓庡鐢点�?/p>
灏界
Li3N
鐨勫娓╃瀛愮數瀵肩巼楂橈紝浣嗗叾鍒嗚В鐢靛帇浣庯紙瀹ゆ俯涓嬩粎鏈?/p>
0.45V
锛夛紝楂樺害鐨勫悇鍚戝紓鎬х粨鏋勶紝鍚堟垚鏃舵槗浜х敓鏉傜浉锛屽绌烘皵鏁忔劅灏?/p>
鍏舵槸閬囨按鏄撶噧绛夛紝
杩欎簺閮介檺鍒朵簡鍏跺湪鍥烘�佺數姹犱腑鐨勫晢涓氬寲搴旂敤銆?/p>
涓烘敼
鍠?/p>
Li3N
鐨勬�ц兘锛屼汉浠鎺烘潅
Li3N
鐨勪竴绯诲垪澶氬厓浣撶郴杩涜浜嗗ぇ閲忕爺绌躲�?/p>
鍦?/p>
Li3N
涓幒鍏?/p>
LiX
锛?/p>
X=Cl,Br,I
锛夊舰鎴?/p>
Li
2-2x
N
0.5-x
X
0.5+x
鍏辩啍浣撳彲鏄捐憲鎻?/p>
楂樺叾鍒嗚В鐢靛帇锛屼粠鑰屾彁楂樹簡鍖栧绋冲畾鎬с�傚湪杩欎竴绯诲垪鎺哄崵鍖栧悎鐗╀腑
Li
9
N
2
Cl
3
鏈�涓哄吀鍨嬶紝
Li
9
N
2
Cl
3
涓虹珛鏂瑰弽钀ょ煶缁撴瀯锛屽叾鏅舵牸涓湁澶х害
10%
鐨勯攤缂洪櫡绌轰綅锛?/p>
Li
+
鏄富瑕佽浇娴佸瓙锛屽娓╃數瀵肩巼涓?/p>
2.5
脳
10
-6
S/cm
锛屽苟
涓斾负涓夌淮绂诲瓙浼犲锛屼紶瀵兼�ц兘鍩烘湰涓哄悇鍚戝悓鎬э紝鐢靛瓙鐢靛鐜囩浉褰撲綆銆?