1
鏈夋満鍖栧悎鐗╁厜璋卞垎鏋愭硶鏁欐
璇剧▼鍚嶇О
鏈夋満鍖栧悎鐗╁厜璋卞垎鏋愭硶
鎺堣鏂瑰紡
鐞嗚璇?/p>
鎺堣瀵硅薄
鎸囧畾閫変慨璇ヨ绋嬬殑
鑽鍜屽埗鑽伐绋嬩笓涓氬鐢?/p>
鎺堣鏃舵暟
30
瀛︽椂
鍒跺畾鏃ユ湡
绗竴娆¤鎺?/p>
璇惧唴瀹?/p>
锛?/p>
2
瀛︽椂锛?/p>
鍓嶈█
鍏夎氨娉曠殑鍙戝睍鍙婂叾搴旂敤
1.
鍥涘ぇ鍏夎氨鐨勪粙缁嶏紙绱
-
鍙鍏夎氨銆佺孩澶栧厜璋便�佹牳纾佸叡鎸拰璐ㄨ氨锛?/p>
锛涘洓澶?
鍏夎氨鐨勫彂灞曞巻鍙层�?/p>
2.
鏈夋満鍖栧悎鐗╁厜璋卞垎鏋愭硶璇剧▼浠嬬粛銆傛湁鏈哄寲鍚堢墿鍏夎氨鍒嗘瀽娉曡绋嬫槸鐮旂┒鍥?
澶у厜璋卞簲鐢ㄤ簬鏈夋満鍖栧悎鐗╃粨鏋勭‘瀹氬強鏈夊叧鐭ヨ瘑鐨勭瀛︺�傚畠鏃㈡槸鍩虹鐞嗚
璇撅紝鍙堟槸搴旂敤鍩虹璇俱�?/p>
3.
閫氳繃瀛︿範鏈绋嬶紝浣垮鐢熻兘姝ｇ‘鎺屾彙鍥涘ぇ鍏夎氨杩涜缁撴瀯纭畾鐨勫師鐞嗗強鍒?
鐢ㄥ叾缁煎悎瑙ｆ瀽鏈夋満鍖栧悎鐗╃粨鏋勭殑鏂规硶锛屼簡瑙ｅ厜璋卞鍙戝睍鐨勬渶鏂板姩鎬佸拰鎶�
鏈�備富瑕佽杩板唴瀹瑰寘鎷湰璇剧▼鐨勫涔犵洰鐨勩�佸涔犲唴瀹广�佺爺绌跺璞°�佸涔?/p>
瑕佺偣銆佸涔犳柟娉曘�佽绋嬪畨鎺掋�佽�冩牳銆佹暀鏉愩�佸弬鑰冧功鍜屾暀甯堢瓑浠嬬粛銆?/p>
4.
缈昏瘧鑻辨枃鍘熺増鏁欐潗鐨勫墠瑷�銆?/p>
绗竴绔?/p>
绱鍙鍏夎氨锛?/p>
UV-Vis
锛?/p>
-
锛?/p>
I
锛?/p>
1.
绱鍙鍏夎氨鐨勫紩璁猴細绱鍙鍏夎氨鐨勪骇鐢?/p>
-
鐢靛瓙鑳界骇璺冭縼銆?/p>
2.
鐢靛瓙璺冭縼鐨勬潯浠讹紝鍏紡琛ㄧず銆?/p>
3.
鍏夌殑鍚告敹瀹氬緥锛?/p>
Lambert-Beer
锛夊拰閫夋嫨瀹氬垯锛?/p>
Selection
rules
锛?/p>
锛氳绠?
鍏紡鍜屽簲鐢ㄦ潯浠躲�?/p>
4.
鍙戣壊鍥㈢殑瀹氫箟锛岀被鍨嬶紝绱鍙鍏夎氨鐮旂┒鐨勫彂鑹插洟
-
鍚叡杞弻鍋ワ紝鍙戣壊
鍥㈢殑鏌ユ壘锛堟尝闀胯寖鍥达紝鍚告敹甯︾殑寮哄害锛?/p>
銆?/p>
5.
婧跺墏鐨勯�夋嫨鍜屾憾鍓傜殑鏋佹�у娉㈤暱鐨勫奖鍝嶏紝绾㈢Щ锛屽叞绉荤殑姒傚康銆?/p>
绗簩娆¤鎺?/p>
璇惧唴瀹?/p>
锛?/p>
2
瀛︽椂锛?/p>
绗竴绔?/p>
绱鍙鍏夎氨锛?/p>
UV-Vis
锛?/p>
-
锛?/p>
II
锛夊嚑绉嶉噸瑕佺殑鍙戣壊鍥?/p>
1.
鍏辫江浜岀儻绫伙紝
Woodward
瀹氬垯棰勬祴鏈�澶у惛鏀舵尝闀垮拰搴旂敤瀹炰緥銆?/p>
2.
伪
,
尾
涓嶉ケ鍜岄叜绫诲拰閱涚被鐨?/p>
蟺
鈫?/p>
蟺
璺冭縼
,
Woodward-Fieser-Scott
瀹氬垯棰?
娴嬫渶澶у惛鏀舵尝闀裤�佸簲鐢ㄥ疄渚嬪強鐩稿叧婧跺墏鏍℃銆?/p>
3.
鍙栦唬鑻殑鍚告敹銆傛渶澶у惛鏀舵尝闀块娴嬪拰搴旂敤瀹炰緥銆?/p>
4.
绱鍏夎氨鐨勫簲鐢細
鏍规嵁绱鍏夎氨鍚告敹宄扮殑浣嶇疆
(
位
max
)
鍜屽惛鏀跺己搴?/p>
(
蔚
)
鎺ㄦ柇
鍙戣壊鍥㈢殑绉嶇被鍜屽叡杞綋绯荤殑闀跨煭
绗笁娆¤鎺?/p>
璇惧唴瀹?/p>
锛?/p>
2
瀛︽椂锛?/p>
绗簩绔?/p>
绾㈠鍏夎氨锛?/p>
IR
锛?/p>
1.
绾㈠鍏夎氨鐨勫紩璁猴細绾㈠鍏夎氨鐨勪骇鐢?/p>
-
鍒嗗瓙鎸姩
-
杞姩鑳界骇璺冭縼銆?/p>
2.
绾㈠鍏夎氨鐨勯�夊緥锛?/p>
Selection rules
锛?/p>
锛屽垽鍒畾鍒欍�傜孩澶栧厜璋辩殑鍑犵鎸姩
褰㈠紡
(
浼哥缉鎸姩銆佸集鏇叉尟鍔ㄧ瓑
)
銆傜孩澶栧厜璋辩殑鎸囩汗鍖哄強閴村畾銆?/p>
3.
鎷夋浖鍏夎氨锛氭媺鏇兼晥搴旓紝绾㈠娲绘�э紝鎷夋浖娲绘�э紝绾㈠鍏夎氨鍜屾媺鏇煎厜璋辩殑鍏?
绯汇�?/p>
4.
浠樼珛鍙跺彉鎹㈢孩澶栧厜璋憋細浠樼珛鍙剁骇鏁板拰鍙樻崲锛屼华鍣ㄤ粙缁嶏紝鍘熺悊鍜岀壒鐐广�?/p>