2019
灞婇珮鑰冨寲瀛︿竴杞涔?/p>
绗叚绔?/p>
鍖栧鍙嶅簲涓庤兘閲?/p>
棰樼粍灞傜骇蹇粌
18
鍖栧鑳戒笌鐑兘
1
锛庡凡鐭ョ儹鍖栧鏂圭▼寮忥細
2SO
2
(g)
锛?/p>
O
2
(g)
2SO
3
(g)
螖
H
锛濓紞
Q kJ
路
mol
锛?/p>
1
(Q>0)
銆備笅鍒楄
娉曟纭殑鏄?/p>
(
)
A
锛庣浉鍚屾潯浠朵笅锛?/p>
2 mol SO
2
(g)
鍜?/p>
1 mol O
2
(g)
鎵�鍏锋湁鐨勮兘閲忓皬浜?/p>
2 mol SO
3
(g)
鎵�鍏锋湁鐨勮兘閲?/p>
B
锛庡皢
2 mol SO
2
(g)
鍜?/p>
1 mol O
2
(g)
缃簬涓�瀵嗛棴瀹瑰櫒涓厖鍒嗗弽搴斿悗锛屾斁鍑虹儹閲忎负
Q kJ
C
锛庤嫢浣跨敤鍌寲鍓傦紝璇ュ弽搴旂殑
|
螖
H|
鍑忓皬
D
锛庡灏嗕竴瀹氶噺
SO
2
(g)
鍜?/p>
O
2
(g)
缃簬鏌愬瘑闂鍣ㄤ腑鍏呭垎鍙嶅簲鍚庢斁鐑?/p>
Q
kJ
锛屽垯姝よ繃绋嬩腑鏈?/p>
2
mol
SO
2
(g)
琚哀鍖?/p>
绛旀
D
2
锛庝竴瀹氭潯浠朵笅锛屽湪姘存憾娑蹭腑
1 mol Cl
锛?
銆?/p>
ClO
x
锛?
(x
锛?/p>
1
锛?/p>
2
锛?/p>
3
锛?/p>
4)
鐨勮兘閲?/p>
(kJ)
鐨勭浉瀵瑰ぇ灏忓
鍥炬墍绀猴紝涓嬪垪鏈夊叧璇存硶姝ｇ‘鐨勬槸
(
)
A
锛?/p>
e
鏄?/p>
ClO
3
锛?
B
锛?/p>
b
鈫?/p>
a
锛?/p>
c
鍙嶅簲鐨勬椿鍖栬兘涓?/p>
60 kJ路mol
锛?/p>
1
C
锛?/p>
a
銆?/p>
b
銆?/p>
c
銆?/p>
d
銆?/p>
e
涓?/p>
c
鏈�绋冲畾
D
锛?/p>
b
鈫?/p>
a
锛?/p>
d
鍙嶅簲鐨勭儹鍖栧鏂圭▼寮忎负
3ClO
锛?
(aq)===ClO
3
锛?
(aq)
锛?/p>
2Cl
锛?
(aq)
螖
H
锛濓紞
116
kJ路mol
锛?/p>
1
绛旀
D
瑙ｆ瀽
A
椤癸紝
c
涓?/p>
Cl
鍏冪礌鍖栧悎浠蜂负锛?/p>
7
浠凤紝鑰?/p>
ClO
3
锛?
涓?/p>
Cl
鍏冪礌鍖栧悎浠蜂负锛?/p>
5
浠凤紝閿欒锛?/p>
B
椤癸紝
b
鈫?/p>
a
锛?/p>
c
鍙嶅簲鐨勬椿鍖栬兘涓?/p>
40 kJ路mol
锛?/p>
1
锛岄敊璇紱
C
椤癸紝
a
銆?/p>
b
銆?/p>
c
銆?/p>
d
銆?/p>
e
涓?/p>
a
鑳介噺鏈�浣庯紝鎵�浠?/p>
鏈�绋冲畾锛?/p>
閿欒锛?/p>
D
椤癸紝
b
鈫?/p>
a
锛?/p>
d
锛?/p>
鏍规嵁杞Щ鐢靛瓙瀹堟亽寰楄鍙嶅簲鏂圭▼寮忎负
3ClO
锛?
===ClO
3
锛?
锛?/p>
2Cl
锛?
锛?/p>
鍙嶅簲鐑紳64 kJ路mol
锛?/p>
1
锛?脳0 kJ路mol
锛?/p>
1
锛?脳60 kJ路mol
锛?/p>
1
锛濓紞116 kJ路mol
锛?/p>
1
锛屾墍浠ヨ鐑?/p>
鍖栧鏂圭▼寮忎负
3ClO
锛?
(aq)===ClO
3
锛?
(aq)
锛?/p>
2Cl
锛?
(aq)
螖
H
锛濓紞116 kJ路mol
锛?/p>
1
锛屾纭�?/p>
3
锛?/p>
(2
017路涔岄瞾鏈ㄩ綈楂樹笁璇婃柇)25 鈩冦�?/p>
101 kPa
鏃讹紝寮洪吀涓庡己纰辩殑绋�婧舵恫鍙戠敓涓拰鍙嶅簲鐨勪腑
鍜岀儹
螖
H
锛濓紞
57.3 kJ/mol
锛岀煶澧ㄧ殑鐕冪儳鐑?/p>
螖
H
锛濓紞
393.5 kJ/mol
锛屼箼閱囩殑鐕冪儳鐑?/p>
螖
H
锛濓紞
1
366.8 kJ/mol
銆備笅鍒楃儹鍖栧鏂圭▼寮忎功鍐欐纭殑鏄?/p>
(
)
A
锛?/p>
2H
锛?
(aq)
锛?/p>
SO
4
2
锛?
(aq)
锛?/p>
Ba
2
锛?
(aq)
锛?/p>
2OH
锛?
(aq)===BaSO
4
(s)
锛?/p>
2H
2
O(l)
螖
H
锛濓紞
57.3 kJ/mol