绗笁绔?/p>
澶氱粍鍒嗙郴缁熺儹鍔涘
涓�銆佸～绌洪
1
銆佸彧鏈夌郴缁熺殑锛匡伎锛匡伎鎬ц川鎵嶅叿鏈夊亸鎽╁皵閲忋�傝�屽亸鎽╁皵閲忚嚜韬槸绯荤粺鐨勶伎锛匡伎锛挎�ц川銆傚亸
鎽╁皵閲忕殑鍊间笌绯荤粺涓悇缁勫垎鐨勬祿搴︼伎锛匡伎锛裤�傛贩鍚堥�傜墿绯荤粺涓悇缁勫垎鐨勫悓涓�鍋忔懇灏旈噺闂?/p>
鍏锋湁涓や釜閲嶈鐨勬�ц川锛屽垎鍒槸锛匡伎锛匡伎涓庯伎锛匡伎锛裤�?/p>
2
銆佸鍚屾俯搴︽槸鐑紶瀵肩殑鎺ㄥ姩鍔涗竴鏍凤紝鍖栧鍔挎槸锛匡伎锛匡伎浼犻�掔殑鎺ㄥ姩鍔涖�傚湪鎭掓俯鎭掑帇涓嬪鐩?/p>
骞宠 鐨勬潯浠舵槸锛匡伎锛匡伎锛匡伎锛匡伎锛匡伎锛匡伎锛匡伎锛匡伎銆備互鐒撹〃绀虹殑缁勫垎
i
鐨勫寲瀛﹀娍鍙啓鎴?/p>
渭
i
=
锛匡伎锛匡伎銆?/p>
3
銆佹贩鍚堢悊鎯虫皵浣撲腑浠讳竴缁勫垎
B
鐨勫寲瀛﹀娍锛匡伎锛匡伎锛匡伎锛匡伎锛涚悊鎯虫憾娑蹭腑浠讳竴缁勫垎
B
鐨勫寲瀛?/p>
鍔匡伎锛匡伎锛匡伎锛匡伎锛匡紱绋�婧舵恫涓憾鍓?/p>
A
鐨勫寲瀛﹀娍锛匡伎锛匡伎锛匡伎锛匡伎銆?/p>
4
銆佺敱绾粍鍒嗗湪鎭掓俯鎭掑帇涓嬬粍鎴愮悊鎯虫贩鍚堢墿鏃讹紝鈻?/p>
mix
S=
锛匡伎
0
锛涒柍
mix
G
锛匡伎
0
锛涒柍
mix
H
锛匡伎
0
锛涒柍
ix
V
锛匡伎
0
銆?/p>
5
銆佺悊鎯虫憾娑叉贩鍚堟椂锛?/p>
飥?/p>
mix
V
锛?/p>
飥?/p>
mix
S
锛?/p>
飥?/p>
mix
G
锛?/p>
飥?/p>
mix
H
銆?/p>
6
銆佹瘮杈冩按鐨勫寲瀛﹀娍鐨勫ぇ灏忥紙姝ゅ
p=101.325kPa
锛夛細锛堝～
>
銆?/p>
<
鎴?/p>
=
锛?/p>
鈶?/p>
渭
(l,100
鈩?/p>
,p)____
渭
(g,100
鈩?/p>
,p)
鈶?/p>
渭
(l,100
鈩?/p>
,p)____
渭
(l,100
鈩?/p>
,2p)
鈶?/p>
渭
(g,100
鈩?/p>
,p)____
渭
(g,100
鈩?/p>
,2p)
鈶?/p>
渭
(l,100
鈩?/p>
,2p)____
渭
(g,100
鈩?/p>
,2p)
鈶?/p>
渭
(l,101
鈩?/p>
,p)____
渭
(g,101
鈩?/p>
,p)
7
銆侀潪鐞嗘兂婧舵恫婧惰川鐨勫寲瀛﹀娍琛ㄧず寮?/p>
____
锛屽叾鏍囧噯鎬佷负
____
銆?/p>
8
銆佸湪涓�瀹氱殑娓╁害鍙婂帇鍔涗笅锛屾煇鐗╄川娑叉苯涓ょ浉杈惧钩琛★紝鍒欎袱鐩哥殑鍖栧鍔?/p>
渭
B
(l)
涓?/p>
渭
B
(g)_____
鑻ョ淮鎸佸帇鍔涗笉鍙橈紝鍗囬珮娓╁害锛屽垯
渭
B
(l)
鍜?/p>
渭
B
(g)
閮?/p>
______
锛涗絾
渭
B
(l)
姣?/p>
渭
B
(g)______
銆?/p>
9
銆佺悊鎯虫憾娑蹭腑浠绘剰缁勫垎
B
鐨勫寲瀛﹀娍锛?/p>
渭
B
=_______________
銆?/p>
10
銆?/p>
298K
銆?/p>
101.325kPa
锛屾湁涓ょ摱钀樼殑鑻憾娑诧紝绗竴鐡朵负
2
鍗囷紝婧舵湁
0.5mol
钀橈紝绗簩鐡朵负
1
鍗囷紝婧舵湁
0.25mol
钀橈紝鑻ヤ互
渭
1
鍜?/p>
渭
2
琛ㄧず涓ょ摱涓悩鐨勫寲瀛﹀娍锛屽垯瀹冧滑鐨勫叧绯讳负
__________
銆?/p>
11
銆佺硸鍙互椤哄埄婧惰В鍦ㄦ按涓紝璇存槑鍥轰綋绯栫殑鍖栧鍔胯緝绯栨按涓殑绯栫殑鍖栧鍔匡伎锛匡伎锛裤�?/p>