鐑偣
3
鍖栧骞宠 甯告暟銆佸钩琛¤浆鍖栫巼鐨勮绠?/p>
1
锛?/p>
CuCl
2
婧舵恫涓殑閾滀富瑕佷互
Cu(H
2
O)
2
锛?/p>
4
銆?/p>
CuCl
2
锛?
4
褰㈠紡瀛樺湪锛屽皢
CuCl
2
婧朵簬娴?/p>
鐩愰吀涓紝
瀛樺湪涓嬪垪骞宠 锛?/p>
Cu(H
2
O)
2
锛?/p>
4
(aq)
锛?/p>
4Cl
锛?
(aq)
CuCl
2
锛?
4
(aq)
锛?/p>
4H
2
O(l)
螖
H
锛?/p>
0
銆?/p>
(1)
璇ュ弽搴旂殑骞宠 甯告暟琛ㄨ揪寮忎负
_______________________
銆?/p>
(2)
甯告俯涓嬶紝
娴嬪畾骞宠 浣撶郴涓細
Cu(H
2
O)
2
锛?
4
娴撳害涓?/p>
a
mol
路
L
锛?/p>
1
銆?/p>
Cl
锛?/p>
娴撳害涓?/p>
b
mol
路
L
锛?/p>
1
銆?/p>
CuCl
2
锛?/p>
4
娴撳害涓?/p>
c
mol
路
L
锛?/p>
1
锛?/p>
Cl
锛?/p>
鐨勮浆鍖栫巼涓?/p>
____________(
鐢ㄥ惈
a
銆?/p>
b
銆?/p>
c
鐨勫瓧
姣嶈〃绀?/p>
)
銆?/p>
绛旀
(1)
c
锛?/p>
CuCl
2
锛?
4
锛?
c
4
锛?/p>
Cl
锛?/p>
锛?/p>
路
c
[Cu
锛?/p>
H
2
O
锛?/p>
2
锛?/p>
4
]
(2)
4
c
b
锛?/p>
4
c
瑙ｆ瀽
(2)
宸茬煡
Cu(H
2
O)
2
锛?
4
(aq)
锛?/p>
4Cl
锛?/p>
(aq)
CuCl
2
锛?
4
(aq)
锛?/p>
4H
2
O(l)
骞宠 浣撶郴
涓細
Cu(H
2
O)
2
锛?/p>
4
娴撳害涓?/p>
a
mol
路
L
锛?/p>
1
銆?/p>
Cl
锛?/p>
娴撳害涓?/p>
b
mol路
L
锛?/p>
1
銆?/p>
CuCl
2
锛?
4
娴撳害涓?/p>
c
mol
路
L
锛?/p>
1
锛?/p>
鍒?/p>
Cl
锛?/p>
鍙樺寲鐨勬祿搴︿负
4
c
mol
路
L
锛?/p>
1
锛?/p>
Cl
锛?/p>
璧峰鐨勬祿搴︿负
(
b
锛?/p>
4
c
)
mol路
L
锛?/p>
1
锛?/p>
Cl
锛?/p>
鐨?
杞寲鐜囦负
4
c
b
锛?/p>
4
c
銆?/p>
2
锛?/p>
T
娓╁害鏃讹紝鍚?/p>
10 L
鎭掑瀵嗛棴瀹瑰櫒涓厖鍏?/p>
2 mol NO
鍜?/p>
2 mol CO
鍙戠敓鍙嶅簲
2NO(g)
锛?/p>
2CO(g)
N
2
(g)
锛?/p>
2CO
2
(g)螖
H
锛濓紞
746.5 kJ路
mol
锛?/p>
1
5 min
鏃惰揪鍒板钩琛★紝娴嬪緱
0
锝?/p>
5 min
鍐呰鍙嶅簲閫熺巼
v
(N
2
)
锛?/p>
0.016 mol路
L
锛?/p>
1
路
min
锛?/p>
1
銆?/p>
(1)
T
娓╁害鏃讹紝璇ュ弽搴旂殑骞宠 甯告暟
K
锛?/p>
________
銆?/p>
(2)
骞宠 鏃跺鍣ㄥ唴鍘嬪己涓庤捣濮嬫椂瀹瑰櫒鍐呭帇寮轰箣姣斾负
________
銆?/p>
绛旀
(1)800
(2)4
鈭?/p>
5
瑙ｆ瀽
(1)
T
娓╁害鏃?/p>
锛?/p>
0
锝?/p>
5
min
鍐呰鍙嶅簲閫熺巼
v
(N
2
)
锛?/p>
0.016
mol路
L
锛?/p>
1
路
min
锛?/p>
1
锛?/p>
鍒欏钩琛℃椂
c
(N
2
)
锛?/p>
0.016 mol
路
L
锛?/p>
1
路
min
锛?/p>
1
脳
5 min
锛?/p>
0.08 mol路
L
锛?/p>
1
锛?/p>
鏍规嵁鏂圭▼寮?/p>
2NO(g)
锛?/p>
2CO(g)
N
2
(g)
锛?/p>
2CO
2
(g)
锛?/p>
骞宠 鏃?/p>
c
(CO
2
)
锛?/p>
0.16 mol路
L
锛?/p>
1
锛?/p>
c
(CO)
锛?/p>
0.04 mol路
L
锛?/p>
1
锛?/p>
c
(NO)
锛?/p>
0.04 mol路
L
锛?/p>
1
锛?/p>
璇ュ弽搴旂殑骞宠 甯告暟
K
锛?/p>
0.16
2
脳
0.08
0.04
2
脳
0.04
2
锛?/p>
800
銆?/p>