绮惧績鏁寸悊
绗崄涓�绔犵數鍖栧鍩虹
11-1
鐢ㄦ哀鍖栨暟娉曢厤骞充笅鍒楁柟绋嬪紡
锛?/p>
1
锛?/p>
KClO
3
飩?/p>
KClO
4
+KCl
锛?/p>
2
锛?/p>
Ca
5
锛?/p>
PO
4
锛?/p>
3
F+C+SiO
2
飩?/p>
CaSiO3+CaF
2
+P
4
+CO
锛?/p>
3
锛?/p>
NaNO
2
+NH
4
Cl
飩?/p>
N
2
+NaCl+H
2
O
锛?/p>
4
锛?/p>
K
2
Cr
2
O
7
+FeSO
4
+H
2
SO
4
飩?/p>
Cr
2
锛?/p>
SO
4
锛?/p>
3
+Fe
2
锛?/p>
SO
4
锛?/p>
3
+K
2
SO
4
+H
2
O
锛?/p>
5
锛?/p>
CsCl+Ca
飩?/p>
CaCl
2
+Cs
瑙ｏ細
锛?/p>
1
锛?/p>
4KClO
3
==3KClO
4
+KCl
锛?/p>
2
锛?/p>
4Ca
5
锛?/p>
PO
4
锛?/p>
3F+30C+18SiO
2
==18CaSiO3+2CaF
2
+3P
4
+30CO
锛?/p>
3
锛?/p>
3NaNO
2
+3NH
4
Cl==3N
2
+3NaCl+6H
2
O
锛?/p>
4
锛?/p>
K
2
Cr
2
O
7
+6FeSO
4
+7H
2
SO
4
==Cr
2
锛?/p>
SO
4
锛?/p>
3
+3Fe
2
锛?/p>
SO
4
锛?/p>
3
+K
2
SO
4
+7H
2
O
锛?/p>
5
锛?/p>
2CsCl+Ca==CaCl
2
+2Cs
11-2
灏嗕笅鍒楁按婧舵恫鍖栧鍙嶅簲鐨勬柟绋嬪紡鍏堟敼涓虹瀛愭柟绋嬪紡锛岀劧鍚庡垎瑙ｄ负涓や釜鍗婂弽搴斿紡锛?/p>
锛?/p>
1
锛?/p>
2H
2
O
2
==2H
2
O+O
2
锛?/p>
2
锛?/p>
Cl
2
+H
2
O==HCl+HClO
锛?/p>
3
锛?/p>
3Cl
2
+6KOH==KClO
3
+5KCl+3H
2
O
锛?/p>
4
锛?/p>
2KMnO
4
+10FeSO
4
+8H
2
SO
4
==K
2
SO
4
+5Fe
2
(SO
4
)
3
+2MnSO
4
+8H
2
O
锛?/p>
5
锛?/p>
K
2
Cr
2
O
7
+3H
2
O
2
+4H
2
SO
4
==K
2
SO
4
+Cr
2
(SO
4
)
3
+3O
2
+7H
2
O
瑙ｏ細
(1)
绂诲瓙寮忥細
2H
2
O
2
==2H
2
O+O
2
H
2
O
2
+2H
飥?
+2e
-
==2H
2
O
H
2
O
2
锛?/p>
2e
-
==O
2
+2H
飥?
锛?/p>
2
锛夌瀛愬紡锛?/p>
Cl
2
+H
2
O==H
+
+Cl
锛?/p>
+HClOCl
2
+2e
-
==2Cl
鈥?/p>
Cl
2
+H
2
O
锛?/p>
2e
-
==2H
+
+2HClO
锛?/p>
3
锛夌瀛愬紡锛?/p>
3Cl
2
+6OH
-
==ClO
3
锛?/p>
+5Cl
-
+3H
2
OCl
2
+2e
-
==2Cl
鈥?/p>
Cl
2
+12OH
锛?/p>
锛?/p>
10e
-
==2ClO
3
锛?/p>
+6H
2
O
锛?/p>
4
锛夌瀛愬紡锛?/p>
MnO
4
-
+5Fe
2+
+8H
+
==5Fe
3+
+Mn
2+
+4H
2
O
MnO
4
-
+5e
-
+8H
+
==Mn
2+
+4H
2
OFe
2+
-e
-
==Fe
3+
锛?/p>
5
绂诲瓙寮忥細
Cr
2
O
7
2
锛?/p>
+3H
2
O
2
+8H
+
==2Cr
3+
+3O
2
+7H
2
O
Cr
2
O
7
2
锛?/p>
+6e
-
+14H
+
==2Cr
3+
+7H
2
OH
2
O
2
锛?/p>
2e
-
==O
2
+2H
飥?
11-3.
鐢ㄥ崐鍙嶅簲娉曪紙绂诲瓙
-
鐢靛瓙娉曪級閰嶅钩涓嬪垪鏂圭▼寮?/p>
锛?/p>
1
锛?/p>
K
2
Cr
2
O
7
+H
2
S+H
2
SO
4
鈥斺�?/p>
K
2
SO
4
+Cr
2
(SO
4
)
3
+H
2
O
锛?/p>
2
锛?/p>
MnO
4
2-
+H
2
O
2
鈥斺�斺�?/p>
O
2
+Mn
2+
锛堥吀鎬ф憾娑诧級
锛?/p>
3
锛?/p>
Zn+NO
3
-
+OH
-
鈥斺�?/p>
NH
3
+Zn
锛?/p>
OH
锛?/p>
4
2-
锛?/p>
4
锛?/p>
Cr
锛?/p>
OH
锛?/p>
4
-
+H
2
O
2
鈥斺�?/p>
CrO
4
2-
锛?/p>
5
锛?/p>
Hg+NO
3
-
+H
+
鈥斺�?/p>
Hg
2
2+
+NO
瑙ｏ細
锛?/p>
1
锛?/p>
K
2
Cr
2
O
7
+3H
2
S+4H
2
SO
4
==K
2
SO
4
+Cr
2
(SO
4
)
3
+7H
2
O+3S
锛?/p>
2
锛?/p>
MnO
4
2-
+2H
2
O
2
+4H
飥?
==2O
2
+Mn
2+
+4H
2
O
锛?/p>
3
锛?/p>
Zn+NO
3
锛?/p>
+3H
2
O+OH
-
==NH
3
+Zn
锛?/p>
OH
锛?/p>
4
2-