1
涓夋隘鍖栧叚姘ㄥ悎閽寸殑鍚堟垚
涓�銆佸疄楠岀洰鐨?/p>
1.
鎺屾彙涓夋隘鍖栧叚姘ㄥ悎閽达紙
III
锛夌殑鍚堟垚銆?/p>
2.
鍔犳繁鐞嗚В閰嶅悎鐗╃殑褰㈡垚瀵逛笁浠烽挻绋冲畾鎬х殑褰卞搷銆?/p>
浜屻�佸疄楠屽師鐞?/p>
鏍规嵁鏈夊叧鐢靛鐨勬爣鍑嗙數鏋佺數浣嶅彲浠ョ煡閬擄紝
鍦ㄩ�氬父鎯呭喌涓嬶紝
浜屼环閽寸洂姣斾笁浠烽挻
鐩愮ǔ瀹氬緱澶氾紝
鑰屽湪璁稿鍦哄悎涓嬪畠浠殑閰嶅悎鐗╂濂界浉鍙嶏紝
涓変环閽村弽鑰屾瘮浜屼环閽存潵寰?/p>
绋冲畾锛岃�屾椿鎬х殑
Co
锛堚叀锛夐厤鍚堢墿寰堝鏄撳舰鎴愩�傚洜姝ら�氬父閲囩敤姘у寲浜屼环閽撮厤鍚堢墿
鐨勬柟娉曪紝鏉ュ埗澶囦笁浠烽挻鐨勯厤鍚堢墿銆?/p>
鑳藉皢
Co
锛堚叀锛?/p>
閰嶅悎鐗╂哀鍖栨垚
Co
锛堚參锛?/p>
閰嶅悎鐗╃殑姘у寲鍓傛湁澶氱锛?/p>
濡傚崵绱犲崟璐紝
浣嗗簲鐢ㄥ崵绱犲仛姘у寲鍓備細寮曞叆鍗ょ礌绂诲瓙
X
-
,
PbO
2
涔熸槸寰堝ソ鐨勬哀鍖栧墏锛?/p>
瀹冨彲琚繕鍘熸垚
Pb
2+
锛屽湪
Cl
-
瀛樺湪鏃讹紝瀹冨彲鎴愪负
PbCl
2
娌夋穩锛屽彲杩囨护闄ゅ幓锛涘悓鏍?/p>
SeO
2
涔熸槸涓�涓緢
濂界殑姘у寲鍓傦紝杩樺師浜х墿
Se
鏄矇娣�锛屽彲杩囨护闄ゅ幓銆傛渶濂界殑姘у寲鍓傛槸绌烘皵锛堢┖姘斾腑
瀵屽惈
O
2
锛夋垨
H
2
O
2
锛屽畠浠笉浼氬紩鍏ユ潅璐ㄣ�?/p>
姘寲閽?/p>
锛堚參锛?/p>
鐨勬皑鍚堢墿鏈夊緢澶氱锛?/p>
涓昏鏈変笁姘寲鍏皑鍚堥挻
锛堚參锛?/p>
[
Co(NH
3
)
6
]Cl
3
锛堟榛勮壊鏅朵綋锛?/p>
锛屼笁姘寲涓�姘翠簲姘ㄥ悎閽达紙鈪級
[Co(NH
3
)
5
H
2
O]Cl
3
锛堢爾绾㈣壊鏅朵綋锛?/p>
锛?/p>
浜屾隘鍖栦竴姘簲姘ㄥ悎閽达紙鈪級
[Co(NH
3
)
5
Cl]Cl
2
锛堢传绾㈣壊鏅朵綋锛夌瓑锛屽畠浠殑鍒跺鏉′欢
鍚勪笉鐩稿悓銆?/p>
鏈疄楠屼互娲绘�х⒊涓哄偓鍖栧墏锛?/p>
鐢ㄨ繃姘у寲姘㈡哀鍖栨湁姘ㄥ拰姘寲閾靛瓨鍦ㄧ殑姘寲閽存憾娑?/p>
鍒跺涓夋隘鍖栧叚姘ㄥ悎閽?/p>
(
鈪?/p>
)
锛屾�诲弽搴斿紡濡備笅锛?/p>
2CoCl
2
路
6H
2
O
锛?/p>
10NH
3
锛?/p>
2NH
4
Cl
锛?/p>
H
2
O
2
===2[Co(NH
3
)
6
]Cl
3
锛?/p>
14H
2
O
涓夋隘鍖栧叚姘ㄥ悎閽存憾瑙ｄ簬閰告�ф憾娑蹭腑锛?/p>
閫氳繃杩囨护鍙互灏嗘贩鍦ㄤ骇鍝佷腑鐨勫ぇ閲忔椿鎬?
鐐櫎鍘伙紝鐒跺悗鍦ㄩ珮娴撳害鐩愰吀涓娇涓夋隘鍏皑鍚堥挻缁撴櫠銆?/p>
涓夋隘鍖栧叚姘ㄥ悎閽村彲婧朵簬姘翠笉婧朵簬涔欓唶锛?/p>
20
鈩?/p>
鍦ㄦ按涓殑婧惰В搴︿负
0.26 mol路
L
-1
[Co(NH
3
)
6
]
3+
绂诲瓙鏄緢绋冲畾鐨勶紝
鍏?/p>
K(
绋?/p>
)
锛?/p>
1.6脳
10
35
锛?/p>
鍥犳鍦ㄥ己纰辩殑浣滅敤涓?/p>
锛堝喎
鏃讹級鎴栧己閰镐綔鐢ㄤ笅鍩烘湰涓嶈鍒嗚В锛屽彧鏈夊姞鍏ュ己纰卞苟鍦ㄦ哺鐑殑鏉′欢涓嬫墠鍒嗚В銆?/p>
2 [Co(NH
3
)
6
]Cl
3
+ 6 NaOH
==== 2 Co(OH)
3
+ 12 NH
3
鈫? 6
NaCl
涓夈�佷华鍣ㄥ拰鑽搧
1.
璇曢獙浠櫒
鎶芥护瑁呯疆銆侀敟褰㈢摱銆?/p>
娓╁害璁★紙
100
0
C
锛?/p>
1
鏀�?/p>
婊寸
銆侀噺绛掞紙
25 ml
锛?/p>
銆佺儳鏉�?/p>
2.
鑽搧