瀹?/p>
楠?/p>
鎶?/p>
鍛?
璇剧▼鍚嶇О锛?/p>
澶у鍖栧瀹為獙
p
瀹為獙绫诲瀷锛?/p>
涓骇鍖栧瀹為獙
瀹為獙椤圭洰鍚嶇О锛?/p>
姘ㄥ熀鐢查吀閾电殑鍒嗚В鍙嶅簲骞宠 甯告暟鐨勬祴瀹?/p>
鍚岀粍瀛︾敓濮撳悕锛?/p>
鏃?/p>
鎸囧鑰佸笀
鍘夊垰
涓�銆佸疄楠岀洰鐨勫拰瑕佹眰
1
銆佺啛鎮夌敤绛夊帇娉曟祴瀹氬浐浣撳垎瑙ｅ弽搴旂殑骞宠 鍘嬪姏銆?/p>
2
銆佹帉鎻＄湡绌哄疄楠屾妧鏈�?/p>
3
銆佹祴瀹氭皑鍩虹敳閰搁摰鍒嗚В鍘嬪姏锛岃绠楀垎瑙ｅ弽搴斿钩琛″父鏁板強鏈夊叧鐑姏瀛﹀嚱鏁般�?/p>
浜屻�佸疄楠屽唴瀹瑰拰鍘熺悊
姘ㄥ熀鐢查吀閾?/p>
(NH
2
COONH
4
)
鏄槸鍚堟垚灏跨礌鐨勪腑闂翠骇鐗╋紝鐧借壊鍥轰綋锛屼笉绋冲畾锛屽姞鐑槗鍙戠敓濡備笅鐨勫垎瑙ｅ弽搴旓細
NH
2
COONH
4
(s)
2NH
3
锛?/p>
g
锛?/p>
+CO
2
锛?/p>
g
锛?/p>
璇ュ弽搴旀槸鍙�嗙殑澶氱浉鍙嶅簲銆傝嫢灏嗘皵浣撶湅鎴愮悊鎯虫皵浣擄紝骞朵笉灏嗗垎瑙ｄ骇鐗╀粠绯荤粺涓Щ璧帮紝鍒欏緢瀹规槗杈惧埌骞?/p>
琛★紝鏍囧噯骞宠 甯告暟
K
p
鍙〃绀轰负锛?/p>
K
p
=
2
3
NH
p
鈥?/p>
2
CO
p
锛?/p>
1
锛?/p>
寮忎腑锛?/p>
3
NH
p
銆?/p>
2
CO
p
鍒嗗埆涓哄钩琛℃椂
NH
3
鍜?/p>
CO
2
鐨勫垎鍘嬶紝鍙堝洜鍥轰綋姘ㄥ熀鐢查吀閾电殑钂告皵鍘嬪彲蹇界暐涓嶈锛屾晠浣撶郴鐨?/p>
鎬诲帇
p
鎬?/p>
涓猴細
p
鎬?/p>
锛?/p>
3
NH
p
锛?/p>
2
CO
p
绉颁负鍙嶅簲鐨勫垎瑙ｅ帇鍔涳紝浠庡弽搴旂殑璁￠噺鍏崇郴鐭?/p>
3
NH
p
锛?/p>
2
2
CO
p
鍒欐湁
3
NH
p
锛?
3
2
p
鎬?/p>
鍜?/p>
2
CO
p
锛?/p>
3
1
p
鎬?/p>
K
p
= (
3
2
p
鎬?/p>
)
2
鈥?/p>
(
3
1
p
鎬?/p>
)
锛?/p>
27
4
3
鎬?/p>
p
锛?/p>
2
锛?/p>
鍙褰撲綋绯昏揪骞宠 鍚庯紝娴嬪緱骞宠 鎬诲帇鍚庡氨鍙眰绠楀疄楠屾俯搴︾殑骞宠 甯告暟
K
p
銆?/p>
骞宠 甯告暟
K
p
绉颁负缁忛獙骞宠 甯告暟銆備负灏嗗钩琛″父鏁颁笌鐑姏瀛﹀嚱鏁拌仈绯昏捣鏉ワ紝鎴戜滑鍐嶅畾涔夋爣鍑嗗钩琛″父鏁般�傚寲
瀛︾儹鍔涘瑙勫畾娓╁害涓?/p>
T
銆佸帇鍔涗负
100kp
a
鐨勭悊鎯虫皵浣撲负鏍囧噯鎬侊紝
100kp
a
绉颁负鏍囧噯鎬佸帇鍔涖�?/p>
3
NH
p
銆?/p>
2
CO
p
鎴?/p>
p
鎬?/p>
闄や互
100kp
a
灏卞緱鏍囧噯骞宠 甯告暟銆?/p>
飦?
p
K
= (
飦?/p>
p
p
鎬?/p>
3
2
)
2
鈥?/p>
(
飦?/p>
p
p
鎬?/p>
3
1
) =
27
4
(
飦?
p
p
鎬?/p>
)
3
=
3
15
10
27
4
鎬?/p>
p
飩?/p>
娓╁害瀵规爣鍑嗗钩琛″父鏁扮殑褰卞搷鍙敤涓嬪紡琛ㄧず锛?/p>
dT
k
d
飦?
ln
=
2
RT
H
m
鈻?/p>
dT
k
d
飦?/p>
ln
锛?/p>
3
锛夊紡涓紝鈻?/p>
H
m
涓虹瓑鍘嬩笅鍙嶅簲鐨勬懇灏旂創鍙樺嵆鎽╁皵鐑晥搴旓紝鍦ㄦ俯搴﹁寖鍥翠笉澶ф椂鈻?/p>
H
m
鍙涓哄父鏁帮紝鐢辩Н鍒嗗緱锛?/p>
ln
飦?
p
K
=
锛?
RT
H
m
鈻?/p>
+C
锛?/p>
4
锛?/p>
浣?/p>
ln
飦?/p>
p
K
-
T
1
鍥惧簲寰椾竴鐩寸嚎锛屾枩鐜?/p>
S=
锛?/p>
R
H
m
鈻?/p>
锛岀敱姝ょ畻寰椻柍
H
m
=
锛?/p>
RS
銆?/p>
鍙嶅簲鐨勬爣鍑嗘懇灏斿悏甯冩柉鍑芥暟鍙樺寲涓庢爣鍑嗗钩琛″父鏁扮殑鍏崇郴涓猴細
涓?/p>
涓氾細
鐞嗙
1010
濮撳悕锛?/p>
闄堜笘鏉?/p>
瀛﹀彿锛?/p>
3100102092
鏃ユ湡锛?/p>
2012.03.5
鍦扮偣锛氬寲瀛﹀疄楠屼腑蹇?/p>
328