1
1
锛堜竴锛夌數鍖栧
涓�銆侀�夋嫨棰?/p>
1
銆佹绂诲瓙鐨勮縼绉绘暟涓庤礋绂诲瓙鐨勮縼绉绘暟涔嬪拰鏄?/p>
(
)
銆?/p>
A.
澶т簬
1
锛?/p>
B.
绛変簬
1
锛?/p>
C.
灏忎簬
1
锛?/p>
D.
鏃犳硶鍒ゆ柇銆?/p>
2
銆佺瀛愮數杩佺Щ鐜囦负涓�瀹氭潯浠朵笅鐨勭瀛愯繍鍔ㄩ�熺巼锛屽嵆锛?/p>
锛?/p>
銆?/p>
A.
鍦ㄦ俯搴︿负
298K
鏃剁殑绂诲瓙杩愬姩閫熺巼锛?/p>
B.
鍦ㄦ祿搴︿负
1mol
路
dm
锛?
3
鏃剁殑绂诲瓙杩愬姩閫熺巼锛?/p>
C.
鍦ㄥ崟浣嶇數鍔挎搴︽椂鐨勭瀛愯繍鍔ㄩ�熺巼锛?/p>
D.
鍦ㄦ祿搴︿负鏃犻檺绋�閲婃椂鐨勭瀛愯繍鍔ㄩ�熺巼銆?/p>
3
銆佹棤闄愮█閲婄殑
KCl
婧舵恫涓紝
Cl
锛?
绂诲瓙鐨勮縼绉绘暟涓?/p>
0.505
锛岃婧舵恫涓?/p>
K
+
绂诲瓙鐨勮縼绉绘暟涓?/p>
(
)
銆?/p>
A. 0.505
锛?/p>
B. 0.495
锛?/p>
C. 67.5
锛?/p>
D. 64.3
銆?/p>
4
銆佺數瑙ｈ川婧舵恫娲诲害
a
B
涓庡叾绂诲瓙骞冲潎娲诲害涔嬮棿鐨勫叧绯讳负锛?/p>
锛?/p>
銆?/p>
A.
a
B
= a
卤
飦?/p>
锛?/p>
B.
a
B
= a
卤
1/
飦?/p>
锛?/p>
C.
a
B
=
锛?/p>
1/
飦?/p>
锛?/p>
a
卤
锛?/p>
D.
a
B
飥?/p>
飦?/p>
a
卤
銆?/p>
5
25
鈩冩棤闄愮█閲婄殑
KCl
鎽╁皵鐢靛鐜囦负
130 S
锕?/p>
m
2
锕?/p>
mol
锛?/p>
1
锛屽凡鐭?/p>
Cl
锛?/p>
鐨勮縼绉绘暟涓?/p>
0.505
锛屽湪
K
+
绂诲瓙鐨勬懇灏旂數瀵肩巼涓猴紙鍗曚綅锛?/p>
S
锕?/p>
m
2
锕?/p>
mol
锛?/p>
1
锛夛紙
锛夈�?/p>
A. 130
锛?/p>
B. 0.479
锛?/p>
C. 65.7
锛?/p>
D. 64.35
銆?/p>
6
銆佺數瑙ｈ川婧舵恫鐨勭瀛愬己搴︿笌鍏舵祿搴︾殑鍏崇郴涓猴紙
锛?/p>
銆?/p>
A.
娴撳害澧炲ぇ锛岀瀛愬己搴﹀寮猴紱
B.
娴撳害澧炲ぇ锛岀瀛愬己搴﹀彉寮憋紱
C.
娴撳害涓嶅奖鍝嶇瀛愬己搴︼紱
D.
闅忔祿搴﹀彉鍖栵紝绂诲瓙寮哄害鍙樺寲鏃犺寰嬨�?/p>
7
25
鈩冩椂锛岀數姹犲弽搴?/p>
Ag
锛?/p>
s
锛?/p>
+ (1/2)Hg
2
Cl
2
(s) = AgCl (s) + Hg (l)
鐨勭數姹犵數鍔ㄥ娍涓?/p>
0.0193 V
锛?
鍙嶅簲鏃舵墍瀵瑰簲鐨勨柍
r
S
m
涓?/p>
32.9 J
路
K
-1
路
mol
-1
锛屽垯鐢垫睜鐢靛姩鍔跨殑娓╁害绯绘暟
p
T
E
)
/
(
飩?/p>
飩?/p>
涓猴紙
锛?/p>
銆?/p>
A.1.70
脳
10
-4
V
路
K
-1
锛?/p>
B. 1.10
脳
10
-6
V
路
K
-1
锛?/p>
C.1.01
脳
10
-1
V
路
K
-1
锛?/p>
D. 3.40
脳
10
-4
V
路
K
-1
銆?/p>
8
銆佸湪
Hittorff
娉曟祴杩佺Щ鏁扮殑瀹為獙涓紝鐢?/p>
Ag
鐢垫瀬鐢佃В
AgNO
3
婧舵恫锛屾祴鍑哄湪闃虫瀬閮?/p>
AgNO
3
鐨?/p>
娴撳害澧炲姞浜?/p>
x
mol
锛岃�屼覆鑱斿湪鐢佃矾涓殑
Ag
搴撲粦璁′笂鏈?/p>
y
mol
鐨?/p>
Ag
鏋愬嚭锛屽垯
Ag
+
绂诲瓙杩佺Щ鏁?/p>
涓?/p>
(
)
銆?/p>
A.
x
/
y
锛?/p>
B.
y
/
x
锛?/p>
C.
(
x
-
y
)/
x
锛?/p>
D.
(
y
-
x
)/
y
銆?/p>
9
銆?/p>
0.1 mol
路
kg
-1
姘寲閽℃按婧舵恫鐨勭瀛愬己搴︿负锛?/p>
锛?/p>
銆?/p>
A.0.1 mol
路
kg
-1
锛?/p>
B.0.15 mol
路
kg
-1
锛?/p>
C.0.2 mol
路
kg
-1
锛?/p>
D.0.3 mol
路
kg
-1
10
銆?/p>
宸茬煡
298 K
鏃讹紝
Hg
2
Cl
2
+ 2e
-
=== 2Hg + 2Cl
-
锛?/p>
1
E
= 0.2676 V
锛?/p>
AgCl + e
-
=== Ag + Cl
-
锛?/p>
2
E
=
0.2224 V
銆傚垯褰撶數姹犲弽搴斾负
Hg
2
Cl
2
+2Ag === 2AgCl + 2Hg
鏃讹紝鍏剁數姹犵殑鏍囧噯鐢靛姩鍔夸负锛?/p>
锛?/p>
A.
-0.0886 V
锛?/p>
B.0.0452 V
锛?/p>
C.
-0.1772 V
锛?/p>
D.0.0276 V
銆?/p>
11
鍦?/p>
25
鈩冩椂锛岀瀛愬己搴︿负
0.015 mol
路
kg
锛?
1
鐨?/p>
ZnCl
2
姘存憾娑蹭腑绂诲瓙骞冲潎娲诲害鍥犲瓙鏄紙
锛?/p>
銆?/p>
A.0.7504
锛?/p>
B.1.133
锛?/p>
C.0.7993
锛?/p>
D.1.283
銆?/p>
12
銆?/p>
0.001 mol
路
kg
锛?/p>
1
K
3
[Fe(CN)
6
]
姘存憾娑茬殑绂诲瓙寮哄害涓猴紙鍗曚綅锛?/p>
mol
路
kg
锛?
1
锛?/p>
锛?/p>
锛?/p>
銆?/p>
A.6.0脳
10
锛?/p>
3
锛?/p>
B.5.0脳
10
锛?/p>
3
锛?/p>
C.4.5脳
10
锛?/p>
3
锛?/p>
D.3.0脳
10
锛?
3
銆?/p>
13
銆佺瀛愭皼鍗婂緞涓庢祿搴﹀叧绯荤殑姝ｇ‘璁鸿堪鏄紙
锛?/p>
銆?/p>
A.
涓庢祿搴︽棤鍏筹紱
B.
闅忔祿搴﹀鍔犺�屽噺灏忥紱
C.
闅忔祿搴﹀鍔犺�屽澶э紱
D.
闅忔祿搴︾殑鍙樺寲鍙噺灏忎篃鍙澶с�?/p>
14
銆佺灏斿姵璁哥瀛愮嫭绔嬭繍鍔ㄥ畾寰嬮�傚悎浜庯紙
锛夈�?/p>
A.
浠绘剰娴撳害鐨勫己鐢佃В璐ㄦ憾娑诧紱
B.
浠绘剰娴撳害鐨勫急鐢佃В璐ㄦ憾娑诧紱
C.
鏃犻檺绋�閲婄殑寮烘垨寮辩數瑙ｈ川婧舵恫锛?/p>
D.
浠绘剰鏉′欢涓嬪潎閫傜敤銆?/p>
15
銆佸湪绛夋俯绛夊帇鐨勭數姹犲弽搴斾腑锛屽綋鍙嶅簲杈惧埌骞宠 鏃讹紝鐢垫睜鐨勭數鍔ㄥ娍绛変簬锛?/p>
锛夈�?/p>
A.
闆讹紱
B.
E
锛?/p>
C.
涓嶄竴瀹氾紱
D.
闅忔俯搴︺�佸帇鍔涚殑鏁板�艰�屽彉銆?/p>
16
銆佸湪璁鸿堪鐢佃В璐ㄧ█婧舵恫鐨?/p>
纬
卤
鏁板�煎ぇ灏忔椂锛屼笅杩拌娉曚腑閿欒鐨勬槸锛?/p>
锛?/p>
銆?/p>
A.
纬
卤
鐨勫ぇ灏忎笌娓╁害鏈夊叧锛?/p>
B.
纬
卤
鐨勫ぇ灏忎笌婧跺墏鎬ц川鏈夊叧锛?/p>
C.
纬
卤
鐨勫ぇ灏忎笌绂诲瓙鐨勪环鏁版棤鍏筹紱
D.
纬
卤
鐨勫ぇ灏忎笌娴撳害鏈夊叧銆?/p>