閰哥⒈鏍囧噯婧舵恫鐨勯厤鍒跺拰鏍囧畾
鍚村績鎮?/p>
(
鐜宸ョ▼
163
鐝?/p>
瀹佹尝
2016013219)
鎽樿
锛?/p>
1
锛夋帉鎻￠吀纰辨爣鍑嗘憾娑茬殑闂存帴閰嶅埗娉曞拰娴撳害鐨勬瘮杈冩淮瀹氥�?/p>
锛?/p>
2
锛夋帉鎻℃淮瀹氭搷浣滐紝鍒濇鎺屾彙鍑嗙‘纭畾缁堢偣鐨勬柟娉曘�?/p>
锛?/p>
3
锛夊浼氭淮瀹氬垎鏋愪腑瀹归噺鍣ㄧ毧鐨勬纭娇鐢ㄣ�?/p>
锛?/p>
4
锛夌啛鎮夋寚绀哄墏鍙樿壊鍘熺悊鍜岀粓鐐归鑹茬殑鍙樺寲锛屽垵姝ユ帉鎻￠吀纰辨寚绀哄墏鐨勯�夋嫨
鏂规硶銆?/p>
鍏抽敭璇?/p>
閰哥⒈骞宠
;
鎸囩ず鍓傦紱閰哥⒈鏍囧畾銆?/p>
1.
寮曡█
閰嶅埗閰哥⒈鏍囧噯婧舵恫鍜岀爺绌堕吀纰卞钩琛℃椂鐨勭姸鎬併�?/p>
2.
瀹為獙閮ㄥ垎
2.1
瀹為獙鍘熺悊
鍦ㄩ吀纰辨淮瀹氫腑锛?/p>
HCl
鍜?/p>
NaOH
鏄渶甯哥敤鐨勬淮瀹氬墏锛屽父鐢ㄤ互閰嶅埗娴撳害涓?/p>
0.1mol/L
鐨勯吀纰辨爣鍑?/p>
婧舵恫銆傛祿鐩愰吀鏄撴尌鍙戞斁鍑?/p>
HCl
姘斾綋鑰屾祿搴︿笉瀹氾紝
NaOH
璇曞墏甯稿惛鏀?/p>
CO
2
鍜屾按钂告皵锛岃瘯鍓傜函搴︿篃
涓嶇‘瀹氾紝鍥犳锛?/p>
HCl
鍜?/p>
NaOH
鏍囧噯婧舵恫涓嶈兘閫氳繃鍑嗙‘绉诲彇娴撶洂閰镐綋绉垨鍑嗙‘绉板彇
NaOH
璐ㄩ噺鐨?/p>
鏂规硶鏉ョ洿鎺ラ厤鍒讹紝閫氬父鍏堥厤鍒舵垚杩戜技
0.1mol/L
娴撳害鐨勬憾娑诧紝鍐嶉�氳繃姣旇緝婊村畾鍜屾爣瀹氭潵纭畾瀹冧滑
鐨勫噯纭祿搴︺�?/p>
NaOH
婧舵恫瀵?/p>
HCl
婧舵恫鐨勬瘮杈冩淮瀹氭槸涓�涓己纰辨淮瀹氬己閰哥殑瀹為獙锛?/p>
鍖栧璁￠噺鐐规椂鐨?/p>
pH
涓?/p>
7.0
锛?/p>
婊村畾鐨勭獊瓒婅寖鍥翠负
pH4.3~9.7
锛岄�夌敤閰氶厼浣滄寚绀哄墏锛屾憾娑茬敱鏃犺壊鍙樹负娴呯矇鑹插嵆涓烘淮瀹氱粓鐐广�?/p>
2.2
浠櫒涓庤瘯鍓?/p>
1.
浠櫒璁惧
FA1104N
鐢靛瓙澶╁钩锛屾墭鐩樺ぉ骞筹紝绉绘恫绠★紙
20mL)
锛岀⒈寮忔淮瀹氱锛?/p>
25mL
锛?/p>
锛岀幓鐠冨缁嗗彛璇曞墏
鐡?/p>
锛?/p>
1000mL
锛?/p>
锛?/p>
姗＄毊濉炵粏鍙ｈ瘯鍓傜摱
锛?/p>
1000mL
锛?/p>
锛?/p>
瀹归噺鐡?/p>
锛?/p>
100mL
锛?/p>
锛?/p>
鐑ф澂
锛?/p>
250mL
锛?/p>
锛?/p>
閲忕瓛
锛?/p>
10mL
锛?/p>
锛?/p>
閿ュ舰鐡讹紙
250mL
锛?/p>
锛岀О閲忕摱锛岀幓妫掞紝绉伴噺绾革紝婊ょ焊銆?/p>
2.
璇曞墏
NaOH
锛?/p>
AR
锛?/p>
锛屾祿鐩愰吀锛?/p>
AR
锛?/p>
锛?/p>
0.1
锛呴厷閰烇紝
0.05%
鐢插熀绾€�?/p>
2.3
瀹為獙鏂规硶
1.
閰哥⒈鏍囧噯婧舵恫鐨勯厤缃?/p>
锛?/p>
1
锛夐厤鍒?/p>
0.1mol/LHCl
婧舵恫
鐢ㄦ磥鍑�閲忕瓛閲忓彇
8.3mL
娴撶洂閰革紝鍊掑叆瑁呮湁绾?/p>
500mL
钂搁姘寸殑璇曞墏鐡朵腑锛屽啀鐢ㄨ捀棣忔按绋�閲婅嚦
1L
锛岀洊涓婄幓鐠冨锛屽厖鍒嗘憞鍖�锛岃创涓婃爣绛惧鐢ㄣ�?/p>
锛?/p>
2
锛夐厤鍒?/p>
0.1mol/LNaOH
婧舵恫
鍦ㄦ墭鐩樺ぉ骞充笂蹇�熺О鍙栧浐浣?/p>
NaOH4g
浜庣儳鏉腑锛岀珛鍗崇敤鏂扮叜娌稿苟鍐峰嵈鑷冲娓╃殑钂搁姘翠娇涔?/p>
婧惰В锛岀◢鍐峰悗杞叆璇曞墏鐡朵腑锛屽姞钂搁姘寸█閲婅嚦
1L
锛岀摱鍙ｇ敤姗＄毊濉炵揣锛屽厖鍒嗘憞鍖�锛岃创涓婃爣绛惧鐢ㄣ�?/p>
2.
閰哥⒈婧舵恫娴撳害鐨勬瘮杈?/p>
锛?/p>
1
锛夌敤
0.1mol/LNaOH
婧舵恫娑︽礂纰卞紡婊村畾绠?/p>
2~3
娆★紝姣忔鐢?/p>
5~10mL
锛岀劧鍚庡皢婧舵恫鍊掑叆婊村畾
绠′腑锛屾帓闄ゆ淮瀹氱绠″皷閮ㄥ垎鐨勬皵娉★紝鍐嶄娇婊村畾绠′腑婧舵恫浣撶Н璇绘暟鍦?/p>
0~1mL
銆?/p>
锛?/p>
2
锛夌敤
20mL
绉绘恫绠＄Щ鍙?/p>
20.00mLHCl
婧舵恫浜庨敟褰㈢摱涓紝鍔犲叆
2
婊撮厷閰炴寚绀哄墏锛岀敤