绗洓绔犮�佽川璋辨硶锛?/p>
122
棰橈級
涓�銆侀�夋嫨棰?/p>
(
鍏?/p>
35
棰?/p>
)
1.
2
鍒?/p>
宸茬煡鏌愬寲鍚堢墿鐨勫垎瀛愬紡涓?/p>
C
8
H
10
锛屽湪璐ㄨ氨鍥句笂鍑虹幇
m
/
z
91
鐨勫己宄帮紝鍒欒鍖栧悎鐗╁彲
鑳芥槸锛?/p>
(
)
2.
2
鍒?/p>
涓嬪垪鍖栧悎鐗╁惈
C
銆?/p>
H
鎴?/p>
O
銆?/p>
N
锛岃瘯鎸囧嚭鍝竴绉嶅寲鍚堢墿鐨勫垎瀛愮瀛愬嘲涓哄鏁?/p>
(
)
(1) C
6
H
(2) C
H NO
(3) C
H NO
(4) C
9
H O
6
6
5
2
4
2
6
10
2
3.
2
鍒?/p>
)
涓嬪垪鍖栧悎鐗╀腑鍒嗗瓙绂诲瓙宄颁负濂囨暟鐨勬槸
(
)
(1) C
6
H
(2) C
H NO
(3) C
H OS
(4) C
6
H N O
6
6
5
2
6
10
2
4
2
4
4.
2
鍒?/p>
鍦ㄦ捍宸辩兎鐨勮川璋卞浘涓紝瑙傚療鍒颁袱涓己搴︾浉绛夌殑绂诲瓙宄帮紝鏈�澶у彲鑳界殑鏄細
(
)
(1)
/
涓?/p>
15
鍜?/p>
29
(2)
/
涓?/p>
93
鍜?/p>
15
m z
m z
(3)
m
/
z
涓?/p>
29
鍜?/p>
95
(4)
m
/
z
涓?/p>
95
鍜?/p>
93
5.
2
鍒?/p>
鍦?/p>
C
2
H
5
F
涓?/p>
, F
瀵逛笅杩扮瀛愬嘲鏈夎础鐚殑鏄?/p>
(
)
(1)
M
(2)
M
+1
(3)
M
+2
(4)
M
鍙?/p>
M
+2
6.
2
鍒?/p>
涓�涓叝鐨勮川璋卞浘鏈?/p>
m
/
z
74(70%)
鐨勫己绂诲瓙宄?/p>
,
涓嬮潰鎵�缁欑粨鏋勪腑鍝釜涓庢瑙傚療鍊兼渶涓轰竴鑷?/p>
(
)
(1) CH
3
CHCHCOOCH
(2) (CH
) CHCOOCH
2
2
3
3
2
3
(3) CH
3
CH
2
COOCH
2
CH
3
(4) (1)
鎴?/p>
(3)
7.
2
鍒?/p>
)
鏌愬寲鍚堢墿鍒嗗瓙寮忎负
C
6
H
14
O,
璐ㄨ氨鍥句笂鍑虹幇
m
/
z
59(
鍩哄嘲
)
m
/
z
31
浠ュ強鍏跺畠
寮卞嘲
m
/
z
73
锛?/p>
m
/
z
87
鍜?/p>
m
/
z
102.
鍒欒鍖栧悎鐗╂渶澶у彲鑳戒负
(
)
(1)
浜屼笝鍩洪啔
(2)
涔欏熀涓佸熀閱?/p>
(3)
姝ｅ繁閱?/p>
(4)
宸遍唶
-2
8.
2
鍒?/p>
鏌愯兒绫诲寲鍚堢墿
,
鍒嗗瓙绂诲瓙宄板叾
=129,
鍏跺己搴﹀ぇ鐨?/p>
/
58(100%), /
100(40%),
鍒欒鍖?/p>
M
m z
m z
鍚堢墿鍙兘涓?/p>
(
)
(1) 4-
姘ㄥ熀杈涚兎
(2) 3-
姘ㄥ熀杈涚兎
(3) 4-
姘ㄥ熀
-3-
鐢插熀搴氱兎
(4) (2)
鎴?/p>
(3)
9.
2
鍒?/p>
鏌愯兒绫诲寲鍚堢墿
,
鍒嗗瓙绂诲瓙宄?/p>
+
=87,
/
30
涓哄熀宄?/p>
,
鍒欏畠鏈�鍙兘鏄?/p>
(
)
M
m z
(1)
(CH
3
)
2
CHCH
2
CH
2
NH
2
CH
3
(2)
CH
3
CH
2
-C-NH
2
CH
CH
3
3