-
-
1
绗?/p>
9
璁?/p>
缁滃悎鐗?/p>
(
閰嶄綅鍖栧悎鐗?/p>
)
鍖栧鍩虹
銆愮珵璧涜姹傘�?/p>
閰嶄綅閿�傞噸瑕佽�屽父瑙佺殑閰嶅悎鐗╃殑涓績绂诲瓙锛堝師瀛愶級鍜岄噸瑕佽�屽父瑙佺殑閰嶄綅锛堟按銆佺緹绂诲瓙銆佸崵
绂诲瓙銆佹嫙鍗ょ瀛愩�佹皑鍒嗗瓙銆侀吀鏍圭瀛愩�佷笉楗卞拰鐑冪瓑锛?/p>
銆傝灟鍚堢墿鍙婅灟鍚堟晥搴斻�傞噸瑕佽�屽父瑙佺殑缁滃悎
鍓傚強鍏堕噸瑕佽�屽父瑙佺殑閰嶅悎鍙嶅簲銆?/p>
閰嶅悎鍙嶅簲涓庨吀纰卞弽搴斻�?/p>
娌夋穩鍙嶅簲銆?/p>
姘у寲杩樺師鍙嶅簲鐨勮仈绯?/p>
锛堝畾鎬?/p>
璇存槑锛?/p>
銆傞厤鍚堢墿鍑犱綍鏋勫瀷鍜屽紓鏋勭幇璞″熀鏈蹇点�傞厤鍚堢墿鐨勬潅鍖栬建閬撶悊璁恒�傚叓闈綋閰嶅悎鐗╃殑鏅朵綋
鍦虹悊璁恒�?/p>
Ti(H
2
O)
飥?
3
6
鐨勯鑹层�傝矾鏄撴柉閰哥⒈鐨勬蹇点�?/p>
銆愮煡璇嗘⒊鐞嗐�?/p>
涓�銆侀厤鍚堢墿鍩烘湰鐭ヨ瘑
1
銆侀厤鍚堢墿鐨勫畾涔?/p>
鐢变腑蹇冪瀛?/p>
锛堟垨鍘熷瓙锛?/p>
鍜屽嚑涓厤浣撳垎瀛?/p>
锛堟垨绂诲瓙锛?/p>
浠ラ厤浣嶉敭鐩哥粨鍚堣�屽舰鎴愮殑澶嶆潅鍒嗗瓙鎴栫
瀛愶紝
閫氬父绉颁负閰嶄綅鍗曞厓銆?/p>
鍑℃槸鍚湁閰嶄綅鍗曞厓鐨勫寲鍚堢墿閮界О浣滈厤浣嶅寲鍚堢墿锛?/p>
绠�绉伴厤鍚堢墿锛?/p>
涔熷彨缁?/p>
鍚堢墿銆?/p>
[Co(NH
3
)
6
]
3+
锛?/p>
[Cr(CN)
6
]
3
鈥?/p>
锛?/p>
Ni(CO)
4
閮芥槸閰嶄綅鍗曞厓锛屽垎鍒О浣滈厤闃崇瀛愩�侀厤闃寸瀛愩�侀厤鍒?/p>
瀛愩�?/p>
[Co(NH
3
)
6
]Cl
3
銆?/p>
K
3
[Cr(CN)
6
]
銆?/p>
Ni(CO)
4
閮芥槸閰嶄綅鍖栧悎鐗┿�?/p>
[Co(NH
3
)
6
]
銆?/p>
[Cr(CN)
6
]
涔熸槸閰?/p>
浣嶅寲鍚堢墿銆傚垽鏂殑鍏抽敭鍦ㄤ簬鏄惁鍚湁閰嶄綅鍗曞厓銆?/p>
鎬濊�冿細涓嬪垪鍖栧悎鐗╀腑鍝釜鏄厤鍚堢墿
鈶?/p>
CuSO
4
路
5H
2
O
鈶?/p>
K
2
P
t
Cl
6
鈶?/p>
KCl
路
CuCl
2
鈶?/p>
Cu(NH
2
CH
2
COO)
2
鈶?/p>
KCl
路
MgCl
2
路
6H
2
O
鈶?/p>
Cu(CH
3
COO)
2
娉ㄦ剰锛氣憼閰嶅悎鐗╁拰閰嶇瀛愮殑鍖哄埆
鈶￠厤鍚堢墿鍜屽鐩愮殑鍖哄埆
2
銆侀厤鍚堢墿鐨勭粍鎴?/p>
涓績绂诲瓙
鍐呯晫
鍗曢娇閰嶄綋
閰嶄綅浣?/p>
澶氶娇閰嶄綋
閰嶅悎鐗?/p>
铻悎閰嶄綋
澶栫晫
锛?/p>
1
锛夐厤鍚堢墿鐨勫唴鐣屽拰澶栫晫
浠?/p>
[Cu(NH
3
)
4
]
SO
4
涓轰緥锛?/p>
[Cu(NH
3
)
4
]
2+
SO
飥?
2
4
鍐呯晫
澶栫晫
鍐呯晫鏄厤浣嶅崟鍏冿紝澶栫晫鏄畝鍗曠瀛愩�傚張濡?/p>
K
3
[Cr(CN)
6
]
涔嬩腑锛屽唴鐣屾槸
[Cr(CN)
6
]
3
鈥?/p>
锛屽鐣屾槸
K
+
銆傚彲浠ユ棤澶栫晫锛屽
Ni(CO)
4
銆備絾涓嶈兘娌℃湁鍐呯晫锛屽唴澶栫晫涔嬮棿鏄畬鍏ㄧ數绂荤殑銆?/p>
锛?/p>
2
锛変腑蹇冪瀛愬拰閰嶄綅浣?/p>
涓績绂诲瓙
:
鍙堢О閰嶅悎鐗╃殑褰㈡垚浣擄紝澶氫负閲戝睘锛堣繃娓￠噾灞烇級绂诲瓙锛屼篃鍙互鏄師瀛愩�傚
Fe
3+
銆?/p>
Fe
2+
銆?/p>
Co
2+
銆?/p>
Ni
2+
銆?/p>
Cu
2+
銆?/p>
Co
绛夛紝鍙鑳芥彁渚涙帴绾冲瀵圭數瀛愮殑绌鸿建閬撳嵆鍙�?/p>
閰嶄綅浣?/p>
:
鍚湁瀛ゅ鐢靛瓙鐨勯槾绂诲瓙鎴栧垎瀛愩�傚
NH
3
銆?/p>
H
2
O
銆?/p>
Cl
锛?/p>
銆?/p>
Br
锛?/p>
銆?/p>
I
锛?/p>
銆?/p>
CN
锛?/p>
銆?/p>
CNS
锛?
绛夈�?/p>
锛?/p>
3
锛夐厤浣嶅師瀛愬拰閰嶄綅鏁?/p>
閰嶄綋涓粰鍑哄瀵圭數瀛愪笌涓績绂诲瓙鐩存帴褰㈡垚閰嶄綅閿殑鍘熷瓙锛?/p>
鍙厤浣嶅師瀛愩�?/p>
閰嶄綅鍗曞厓涓紝
涓績
绂诲瓙鍛ㄥ洿涓庝腑蹇冪瀛愮洿鎺ユ垚閿殑閰嶄綅鍘熷瓙鐨勪釜鏁帮紝鍙厤浣嶆暟銆?/p>
閰嶄綅鍖栧悎鐗?/p>
[Cu(NH
3
)
4
]
SO
4
鐨勫唴鐣屼负
[Cu(NH
3
)
4
]
2+
锛?/p>
涓績
Cu
2+
鐨勫懆鍥存湁
4
涓厤浣?/p>
NH
3
锛?/p>
姣忎釜
NH
3
涓湁
1
涓?/p>
N
鍘熷瓙涓?/p>
Cu
2+
閰嶄綅銆?/p>
N
鏄厤浣嶅師瀛愶紝
Cu
鐨勯厤浣嶆暟
4
銆?/p>
锛堟敞鎰忥細閰嶄綋鐨勪釜
鏁颁笌閰嶄綅鏁颁笉鏄悓涓�涓蹇碉級
鑻ヤ腑蹇冪瀛愮殑鐢佃嵎楂橈紝
鍗婂緞澶э紝
鍒欏埄浜庡舰鎴愰珮閰嶄綅鏁扮殑閰嶄綅鍗曞厓锛?/p>
鑰岄厤浣撶殑鐢佃嵎楂橈紝
鍗婂緞
澶э紝鍒╀簬浣庨厤浣嶆暟銆?/p>
锛?/p>
4
锛夊父瑙佺殑閰嶄綋
鍗曢娇閰嶄綋锛氫竴涓厤浣撲腑鍙兘鎻愪緵涓�涓厤浣嶅師瀛愪笌涓績绂诲瓙鎴愰敭銆傚
H
2
O
銆?/p>
NH
3
銆?/p>
CO
绛夈�?