- 1 -
璇剧▼鍚嶇О锛氭櫘閫氬寲瀛︼紙
A
锛夊嵎
涓�銆佸～绌洪锛堟瘡绌?/p>
2
鍒嗭紝鍏?/p>
30
鍒嗭級
1
.
鍙嶅簲
2MnO
4
-
(aq) + 10Cl
-
(aq) + 16H
+
(aq) = 2Mn
2+
(aq) + 5Cl
2
+8H
2
O(l)
鐨勬爣鍑?/p>
骞宠 甯告暟琛ㄨ揪寮忎负
K
莹
锛?/p>
________________________________________
銆?/p>
2
.
宸茬煡鍙嶅簲
2NO+Cl
2
鈫?/p>
2
NOCl
涓哄熀鍏冨弽搴旓紝鍏堕�熺巼鏂圭▼寮忎负
______________
锛?/p>
鎬诲弽搴旀槸
_____________
绾у弽搴斻�?/p>
3
.
鏈変笅鍒楀師鐢垫睜
:
(-)Pt|Fe
2+
(
1mol/dm
3
),Fe
3+
(0.01mol/dm
3
)||Fe
2+
(
1mol/dm
3
),Fe
3+
(
1mol/dm
3
)|
Pt
(+),
璇ュ師鐢垫睜鐨勮礋鏋佸弽搴斾负
___________________,
姝ｆ瀬鍙嶅簲涓?/p>
__________________
銆?/p>
4.
瀵逛笅鍒楀嚑绉嶆按婧舵恫
,
鎸夊叾鍑濆浐鐐圭敱浣庡埌楂樼殑椤哄簭鏄?/p>
___________________
銆?/p>
A. 0.1mol.Kg
-1
C
6
H
12
O
6
B. 1mol.Kg
-1
C
6
H
12
O
6
C. 0.1mol.Kg
-1
NaCl
D. 1mol.Kg
-1
NaCl
E. 0.1mol.Kg
-1
CaCl
2
F.
0.1mol.Kg
-1
HAc
5.
鐔靛噺灏忕殑鍙嶅簲鍦ㄤ綆娓╀笅鍙嚜鍔ㄨ繘琛岋紝姝ゅ弽搴旂殑
鈭?/p>
r
H
m
_______(>
鎴?/p>
<
鎴?/p>
=0)
銆?/p>
6
.
鏍规嵁閰哥⒈璐ㄥ瓙鐞嗚锛屽湪
H
2
S
銆?/p>
HC
2
O
4
-
銆?/p>
CN
-
銆?/p>
HCN
銆?/p>
H
2
O
銆?/p>
CH
4
銆?/p>
H
2
PO
4
-
銆?/p>
Ac
-
銆?/p>
NH
4
+
銆?/p>
OH
-
銆?/p>
HCO
3
-
绛夌墿璐ㄤ腑锛屼粎灞炰簬纰辩殑鏈?/p>
_____________________
锛?/p>
浠呭睘浜庨吀鐨勬湁
__________________________
銆?/p>
7.
40cm
3
0.1mol.dm
-3
姘ㄦ按涓?/p>
40cm
3
0.1mol.dm
-3
鐩愰吀娣峰悎锛屾憾娑茬殑
pH
鍊间负
____
锛?/p>
40cm
3
0.1mol.dm
-3
姘ㄦ按涓?/p>
20cm
3
0.1mol.dm
-3
鐩愰吀娣峰悎锛屾憾娑茬殑
pH
鍊间负
____
銆?/p>
宸茬煡
K
a
(NH
4
+
)=5.65脳
10
-10
8
.
璁?/p>
AgCl
鍦ㄦ按涓紝鍦?/p>
0.01 mol
路
dm
-3
鐨?/p>
CaCl
2
涓紝鍦?/p>
0.01 mol
路
dm
-3
鐨?/p>
NaCl
涓互鍙婂湪
0.05 mol.dm
-3
鐨?/p>
AgNO
3
涓殑婧惰В搴﹀垎鍒负
S
0
,S
1
,S
2
鍜?/p>
S
3
锛岃繖浜涢噺涔嬮棿鐨勫ぇ灏忔帓鍒楅『搴?/p>
鏄?/p>
_______________________
銆?/p>
9.
宸茬煡鍙嶅簲锛?/p>
C(
鐭冲ⅷ
) + O
2
(g) = CO
2
(g)
鐨?/p>
螖
r
H
m
萤
(298.15K)
=
-
394 kJ路
mol
锛?/p>
1
鍜屽弽搴?/p>
C(
閲戝垰鐭?/p>
)
+
O
2
(g)
=
CO
2
(g)
鐨?/p>
螖
r
H
m
萤
(298.15K)
=
-
396
kJ路
mol
锛?/p>
1
锛屽垯閲戝垰鐭崇殑
螖
f
H
m
萤
(298.15K) = _____ kJ路
mol
锛?/p>
1
銆?/p>
10
锛?/p>
鏌愬熀鎬佸師瀛愮殑鐢靛瓙鏋勫瀷婊¤冻閲忓瓙鏁?/p>
n=4
锛?/p>
l=0
鐨勭數瀛愭湁
2
涓紝
n=3
锛?/p>
l=2
鐨勭數瀛愭湁
6
涓紝
鍏跺厓绱犲悕绉颁负
锛屽湪鍏冪礌鍛ㄦ湡琛ㄤ腑鐨勪綅缃?/p>
_____________________(
鍑犲懆鏈熴�佸嚑
鏃忋�佸嚑鍖?/p>
)
銆?/p>