绗簩绔?/p>
璐ㄨ氨涔犻鍙婄瓟妗?/p>
瑙ｏ細
A
銆?/p>
C
2
H
3
Cl
锛?/p>
B
銆?/p>
C
2
H
6
S
鍒嗗瓙绂诲瓙宄颁负鍋舵暟琛ㄦ槑鍚湁鍋舵暟涓爱鎴栦笉鍚爱銆?/p>
C
x
H
y
N
z
O
w
S
S
涓嶅惈姘?/p>
鍚爱
2
2
RI(M+1)
100
1.1
0.37
0.8
RI(M)
RI(M+2)
(1.1
)
100
0.2
4.4
RI(M)
200
x
z
s
x
w
s
飩?/p>
飥?/p>
飥?/p>
飥?/p>
飩?/p>
飥?/p>
飥?/p>
飥?/p>
2
2
RI(M+1)
100
1.1
0.37
0.8
RI(M)
RI(M+2)
(1.1
)
100
0.2
4.4
RI(M)
200
x
z
s
x
w
s
飩?/p>
飥?/p>
飥?/p>
飥?/p>
飩?/p>
飥?/p>
飥?/p>
飥?/p>
A
銆?
RI(M+1)
4.8
100
1.1
0.37
100
RI(M)
100
x
z
飩?/p>
飥?/p>
飥?/p>
飥?/p>
飩?/p>
锛岃
z=1
锛屽垯
x=4.02
锛?/p>
C
4
N
鍒嗗瓙閲忥紴
62
锛屼笉
鍚堢悊銆傛墍浠ユ棤姘厓绱犮�?/p>
鍚岀悊
B
锛岃
z=1
锛屽垯
x=3.11
锛?/p>
C
3
N
鍒嗗瓙閲忥紴
62
锛屼笉鍚堢悊銆傛墍浠ユ棤姘厓绱犮�?/p>
鍚屼綅绱犵浉瀵逛赴搴﹁〃锛?/p>
p26
琛?/p>
2.3
銆?/p>
瀵逛簬
A
锛?/p>
RI
鐩稿涓板害锛?/p>
M
锛?/p>
(M+2)=3:1
锛屽垯
A
涓湁姘師瀛愶紝鎺ㄦ柇鍏跺垎瀛愬紡涓?/p>
CH
2
=CHCl
瀵逛簬
A
锛?/p>
RI
鐩稿涓板害锛?/p>
M
锛?/p>
(M+2)=25:1
锛屽垯
A
涓湁纭師瀛愶紝鎺ㄦ柇鍏跺垎瀛愬紡
CH
3
CH
2
SH
瑙ｏ細
C
2
H
2
Cl
2
锛?/p>
ClCH=CHCl
m/z=98
鍒嗗瓙绂诲瓙宄帮紝
M
锛?/p>
(M+2)=6:1
锛屾湁涓や釜姘�傚悓浣嶇礌鐩稿涓板害琛紝
p26
琛?/p>
2.3
銆?/p>
M-35=98-Cl
锛?/p>
M-36=98-HCl
锛?/p>
M-37=98-HCl-H
瑙ｏ細
m/z 142=M
飥?/p>
43(
飪?/p>
C
3
H
7
)
锛?/p>
m/z 142=C
9
H
20
N
锛?/p>
(n-C
4
H
9
)
3
N,
鍒嗗瓙绂诲瓙宄颁负濂囨暟琛ㄦ槑鍚湁濂囨暟涓爱銆?/p>