1
涓浗绉戝鎶�鏈ぇ瀛?/p>
涓�涔濅節鍏勾鎷涙敹纭曞＋瀛︿綅鐮旂┒鐢熷叆瀛﹁�冭瘯璇曢
璇曢鍚嶇О锛氱墿鐞嗗寲瀛?/p>
涓�锛庨�夋嫨棰橈紙
10
鍒嗭級
1
锛?/p>
鍦?/p>
298K
鏃讹紝
钂告皵鑻湪鐭冲ⅷ涓婄殑鍚搁檮銆?/p>
绗﹀悎
Langmuir
鍚搁檮绛夋俯寮忥紝
鍦?/p>
40Pa
锛?/p>
瑕嗙洊搴?/p>
飦?/p>
锛?/p>
0.05
鏃惰嫰姘斾綋鐨勫钩琛″帇鍔涗负
锛?/p>
锛?/p>
锛?/p>
A
锛?/p>
400Pa,
(B)760Pa,
(C)1000Pa,
(D)200Pa
2
锛?/p>
瀵逛簬鏈夎繃閲?/p>
KI
瀛樺湪鐨?/p>
AgI
婧惰兌锛岀數瑙ｈ川鑱氭矇鑳藉姏鏈�寮虹殑鏄?/p>
锛?/p>
锛?/p>
(A)
飦?/p>
飦?/p>
3
6
K
Fe(CN)
,
(B)
4
MgSO
(C)
3
FeCl
(D)NaCl.
3.
25
鈩冩椂锛?/p>
鍚屾祿搴︾█婧舵恫
LiI
銆?/p>
HI
銆?/p>
LiCl
涓殑鎽╁皵鐢靛鐜?/p>
+
m
m
m
(LiI)
(H
)
(LiCl)
飦?/p>
飦?/p>
飦?/p>
銆?/p>
銆?/p>
鍊煎垎鍒负
2
2
2
2
-1
1.17
10
3.50
10
1.15
10
S
m
mol
,
飥?/p>
飥?/p>
飥?/p>
飩?/p>
飩?/p>
飩?/p>
飪?/p>
飪?/p>
銆?/p>
鍜?/p>
LiCl
涓殑
Li
+
杩佺Щ鏁颁负
0.34
锛岃鍏朵腑鐨?/p>
鐢佃В璐ㄥ畬鍏ㄧ數绂伙紝鍒?/p>
HI
涓?/p>
H
+
鐨勮縼绉绘暟涓?/p>
锛?/p>
锛?/p>
锛?/p>
A
锛?/p>
0.18
锛?/p>
B
锛?/p>
0.82
锛?/p>
C
锛?/p>
0.34
(D)0.66
4.
婧惰兌涓庡ぇ鍒嗗瓙婧舵恫鐨勭浉鍚岀偣鏄?/p>
(
)
(A)
鏄儹鍔涘绋冲畾浣撶郴
(B)
鏄儹鍔涘涓嶇ǔ瀹氫綋绯?/p>
(C)
鏄姩鍔涘绋冲畾浣撶郴
(D)
鏄姩鍔涘涓嶇ǔ瀹氫綋绯?/p>
5
锛庡弽搴?/p>
A
1
2
B(I);A
D(II).
k
k
飩撅偩
飩?/p>
飩撅偩
飩?/p>
宸茬煡鍙嶅簲
(I)
鐨勬椿鍖栬兘
E
1
澶т簬鍙嶅簲
(II)
鐨勬椿鍖栬兘
E
2
锛?
浠ヤ笅鎺柦涓摢涓�绉嶄笉鑳芥敼鍙樿幏寰?/p>
B
鍜?/p>
D
鐨勬瘮渚嬶紵
(
)
(A)
鎻愰珮鍙嶅簲娓╁害
(B)
寤堕暱鍙嶅簲鏃堕棿
(C)
鍔犲叆閫傚綋鍌寲鍓?/p>
(D)
闄嶄綆鍙嶅簲娓╁害
浜屻�佽绠楅
1
锛?/p>
(5
鍒?/p>
)
绛夋俯绛夊帇
(298.15K
锛?/p>
p
飦?
)
鏉′欢涓嬶紝鏌愪竴鍖栧鍙嶅簲鍦ㄤ笉浣滈潪浣撶Н鍔熸潯浠朵笅杩涜锛?/p>
鏀剧儹
40.0kJ
飪?/p>
mol
-1
锛岃嫢璇ュ弽搴旈�氳繃鍙�嗙數姹犳潵瀹屾垚锛屽垯鍚哥儹
4.00 kJ
飪?/p>
mol
-1
锛屾眰璇ュ寲瀛﹀弽搴旂殑鐔?/p>
鍙?/p>
r
m
S
飦?/p>
飦?
銆?/p>
2
锛?/p>
(12
鍒?/p>
) 1mol
娑蹭綋
A
锛屽湪
p
飦?
鍙婃甯告哺鐐?/p>
T
b
涓嬶紝鍦ㄧ湡绌哄鍣ㄤ腑钂稿彂锛屾渶缁堝彉涓轰笌鍒濇�佸悓
娓?/p>
(
T
b
)
銆佸悓鍘?/p>
(
p
飦?
)
鐨?/p>
1mol
钂告皵
A
銆傝钂告皵涓虹悊鎯虫皵浣擄紝涓庢皵浣撲綋绉浉姣斻�傛恫浣撶殑浣撶Н鍙拷