鍖椾含鍖栧伐澶у
鏀昏纭曞＋瀛︿綅鐮旂┒鐢熷叆瀛﹁�冭瘯
鐗╃悊鍖栧鏍烽
娉ㄦ剰浜嬮」
1
锛庣瓟妗堝繀椤诲啓鍦ㄧ瓟棰樼焊涓婏紝
鍐欏湪璇曞嵎涓婂潎涓嶇粰鍒?/p>
锛庯紟锛庯紟锛庯紟锛庯紟锛?
銆?/p>
2
锛庣瓟棰樻椂鍙笉鎶勯锛屼絾蹇呴』鍐欐竻棰樺彿銆?/p>
3
锛庣瓟棰樺繀椤荤敤钃濄�侀粦澧ㄦ按绗旀垨鍦嗙彔绗旓紝鐢ㄧ孩绗旀垨閾呯瑪鍧囦笉缁欏垎銆?/p>
4
锛庢尝灏斿吂鏇煎父鏁?/p>
k
=1.381
脳
10
-23
J
飪?/p>
K
-1
,
娉曟媺绗父鏁?/p>
F=96500 C
銆?/p>
涓�銆侀�夋嫨棰?/p>
1
锛?/p>
灏?/p>
1mol
鍦ㄦ俯搴?/p>
T
鍙婂叾楗卞拰钂告苯鍘?/p>
p
*
涓嬬殑
H
2
O(l)
鍒嗗埆缁忚繃绋?/p>
I
锛?/p>
绛夋俯銆?/p>
绛夊帇钂稿彂鍙婅繃绋?/p>
II
锛?/p>
鍚戠湡绌鸿捀鍙戯紝鍙樹负鐩稿悓娓╁害銆佺浉鍚屽帇鍔涗笅鐨?/p>
H
2
O(g)
銆備笅鍒楀叧绯绘纭殑鏄?/p>
銆?/p>
A
锛?/p>
螖
G
(I)
飩?/p>
螖
G
(II)
锛?/p>
螖
H
(I) =
Q
(I)
锛?/p>
螖
H
(II)
飩?/p>
Q
(II)
B
锛?/p>
螖
G
(I) =
螖
G
(II)
锛?/p>
螖
U
(I) =
Q
(I)
锛?/p>
螖
H
(I) =
螖
H
(II)
C
锛?/p>
螖
G
(I) =
螖
G
(II)
锛?/p>
螖
H
(I)=
螖
U
(I)
锛?/p>
螖
H
(II)
飩?/p>
Q
(II)
D
锛?/p>
螖
G
(I) =
螖
G
(II)
锛?/p>
螖
H
(I)=
Q
(I)
锛?/p>
螖
H
(II)
飩?/p>
Q
(II)
2
锛庡灏侀棴绯荤粺锛屼笅鍒楄嚜鍙戞�у垽鎹笉姝ｇ‘
锛庯紟锛?/p>
鐨勬槸
銆?/p>
A
锛庣瓑娓╀笖
W
'=0
鐨勮繃绋嬶細
螖
A
鈮?/p>
W
浣撶Н
B
锛庣瓑娓╃瓑鍘嬩笖
W
'=0
鐨勮繃绋嬶細
螖
G
鈮?/p>
0
C
锛庝换鎰忚繃绋嬶細
螖
S
闅旂
=
螖
S
绯荤粺
+
螖
S
鐜
鈮?/p>
0
D
锛庢亽鐔垫亽瀹硅繃绋嬶細
螖
U
鈮?/p>
W
'
3
锛庝笅鍒楁湁鍏冲亸鎽╁皵鐗╃悊閲忓拰鍖栧鍔跨殑璇存硶涓嶆纭殑鏄細
A
锛庡亸鎽╁皵鐗╃悊閲忎负鎭掓俯鎭掑帇涓嬪鍔?/p>
1mol
鏌愮墿璐ㄧ殑閲忓瀹归噺鎬ц川鐨勮础鐚�?/p>
B
锛庢煇鐗╄川鍦?/p>
T
銆?/p>
p
鏉′欢涓嬭揪姘旀恫骞宠 鏃讹紝鍏舵皵鎬佸寲瀛﹀娍涓庢恫鎬佸寲瀛﹀娍鐩哥瓑
C
锛庣悊鎯虫恫鎬佹贩鍚堢墿鍦?/p>
T
銆?/p>
p
鏉′欢涓嬫贩鍚堣繃绋嬫棤鍚搞�佹斁鐑幇璞″強鏃犱綋绉彉鍖?/p>
D
锛庢亽娓╂亽鍘嬩笅锛岀墿璐ㄨ嚜鍙戣繘琛岀殑鏂瑰悜鏄悜鐫�鍖栧鍔垮噺灏忕殑鏂瑰悜杩涜
4
锛庡浜庣悊鎯虫恫鎬佹贩鍚堢墿鐨勬贩鍚堣繃绋嬶紝娣峰悎鍓嶅悗涓嬪垪鍏崇郴姝ｇ‘鐨勬槸
銆?/p>
A
锛?/p>
螖
V
=0
锛?/p>
螖
H
=0
锛?/p>
螖
S
>0
锛?/p>
螖
G
<0
B
锛?/p>
螖
V
<0
锛?/p>
螖
H
>0
锛?/p>
螖
S
>0
锛?/p>
螖G
<0
C
锛?/p>
螖
V
<0
锛?/p>
螖
H
>0
锛?/p>
螖
S
<0
锛?/p>
螖G
>0
D
锛?/p>
螖
V
=0
锛?/p>
螖
H
=0
锛?/p>
螖
S
<0
锛?/p>
螖G
>0
5
锛庣⒊閰搁挋鍒嗚В鍙嶅簲锛?/p>
CaCO
3
(s)
鈫扖aO
(s)+CO
2
(g)
锛屼笉鍚屾俯搴︽椂鐨勬爣鍑嗗钩琛″父鏁板涓嬭〃锛?/p>
T
/
鈩?/p>
600
897
1000
1200
K
飦?/p>
2.45
脳
10
-3
1.013
3.92
29.1
涓嬪垪琛ㄨ揪姝ｇ‘鐨勬槸
銆?/p>
A
锛庤鍙嶅簲鐨勫垎瑙ｆ俯搴︽槸
897
鈩?/p>
B
锛?/p>
1200
鈩冩椂鍒嗚В鍘嬪姏涓?/p>
29.1脳
10
-2
kPa
C
锛?/p>
600
鈩冩椂璇ュ弽搴旂殑骞宠 鍘嬪姏涓?/p>
2.45
脳
10
-3
kPa
D
锛庤鍙嶅簲涓烘斁鐑弽搴旈檷浣庢俯搴︽湁鍒╀簬鍙嶅簲杩涜
6
锛庡弽搴斿櫒鍐呮斁鍏?/p>
N
2
(g)
銆?/p>
O
2
(g)
鍙婁竴绉嶅浐浣撳偓鍖栧墏锛屽弽搴旇揪骞宠 鏃剁敓鎴愪袱绉嶆皵鎬佹爱姘у寲鐗╋紝
绯荤粺鐨勭嫭绔嬬粍鍒嗘暟銆佺浉鏁板強鑷敱搴︽暟鍒嗗埆涓猴細
銆?/p>
A
锛?/p>
3
锛?/p>
3
锛?/p>
2
B
锛?/p>
3
锛?/p>
2
锛?/p>
3
C
锛?/p>
2
锛?/p>
2
锛?/p>
2
D
锛?/p>
2
锛?/p>
3
锛?/p>
1