鈥︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︿笓涓氳祫鏂欐帹鑽愨�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�︹�?/p>
1
鏍哥鍏辨尟姘㈣氨浣滀笟
涓�銆佸悕璇嶈В閲?/p>
1
锛屽鏇兼晥搴旓紱
2
锛屾牳纾佸叡鎸紱
3
锛屽睆钄芥晥搴旓紱
4
锛屽寲瀛︿綅绉伙紱
5
锛岃嚜鏃?/p>
-
鑷棆鍋跺悎锛?/p>
6
锛?/p>
n+1
瑙勫緥锛?/p>
7
锛屽悇鍚戝紓鎬ф晥搴?/p>
浜屻�佸浜岃嫰涔欎簩閰殑姘㈣氨淇″彿杩涜鎸囪
(
婧跺墏锛?/p>
CDCl
3
)
銆?/p>
涓夈�佸
2-
姘ㄥ熀鍚″暥鐨勮姵姘俊鍙疯繘琛屾寚璁ゃ�?/p>
鍥涖�佸
1-
鐢叉哀鍩?/p>
-4
鐢插熀鎴婄兎鐨?/p>
1
HNMR
妯℃嫙鍥捐氨杩涜鎸囪銆?/p>
0
1
2
3
PPM
浜旓紝鍒嗗瓙寮忎负
C
2
H
2
BrCl
鐨勫寲鍚堢墿鐨?/p>
1
HNMR (300 MHz, CDCl
3
)
未
: 6.50 (d,
J
= 16.0 Hz, 1H),
6.78 (d,
J
= 16.0 Hz, 1H)
锛岃瘯鎺ㄦ祴鍖栧悎鐗╃殑鍙兘缁撴瀯锛屽苟纭畾绔嬩綋鏋勫瀷銆?/p>
鍏紝鏈変笁涓垎瀛愬紡涓?/p>
C
9
H
12
O
鐨勫悓鍒嗗紓鏋勪綋锛屽叾
1
HNMR (300 MHz, CDCl
3
and 1d D
2
O)
濡備笅锛?/p>
璇曞垽鏂笁涓浘璋卞垎鍒搴斿紓鏋勪綋鐨勭粨鏋勩�?/p>
O
O
N
NH
2
O