1
鐩愮被鐨勬按瑙ｅ拰娌夋穩婧惰В骞宠
A
鍗?/p>
鍏ㄥ浗鍗?/p>
鐢佃В璐ㄦ憾娑蹭腑寰矑娴撳害鐨勫叧绯?/p>
1
锛?/p>
(2014路璇炬爣鍏ㄥ浗鈪★紝
11
锛?/p>
6
鍒?/p>
)
涓�瀹氭俯搴︿笅锛?/p>
涓嬪垪婧舵恫鐨勭瀛愭祿搴﹀叧绯诲紡姝ｇ‘鐨勬槸
(
)
A
锛?/p>
pH
锛?/p>
5
鐨?/p>
H
2
S
婧舵恫涓紝
c
(H
锛?/p>
)
锛?/p>
c
(HS
锛?/p>
)
锛?脳10
锛?/p>
5
mol路L
锛?/p>
1
B
锛?/p>
pH
锛?/p>
a
鐨勬皑姘存憾娑诧紝绋�閲?/p>
10
鍊嶅悗锛屽叾
pH
锛?/p>
b
锛屽垯
a
锛?/p>
b
锛?/p>
1
C
锛?/p>
pH
锛?/p>
2
鐨?/p>
H
2
C
2
O
4
婧舵恫涓?/p>
pH
锛?/p>
12
鐨?/p>
NaOH
婧舵恫浠绘剰姣斾緥娣峰悎锛?/p>
c
(Na
锛?/p>
)
锛?/p>
c
(H
锛?/p>
)
锛?/p>
c
(OH
锛?
)
锛?/p>
c
(HC
2
O
锛?
4
)
D
锛?/p>
pH
鐩稿悓鐨勨憼CH
3
COONa
鈶aHCO
3
鈶aClO
涓夌婧舵恫鐨?/p>
c
(Na
锛?
)
锛氣憼>鈶?gt;鈶?/p>
瑙ｆ瀽
H
2
S
鏄簩鍏冨急閰革紝鍦ㄦ按婧舵恫涓垎姝ョ數绂伙細
H
2
S
H
锛?/p>
锛?/p>
HS
锛?/p>
銆?/p>
HS
锛?
H
锛?
锛?
S
2
锛?
锛屾晠
pH
锛?/p>
5
鐨?/p>
H
2
S
婧舵恫涓紝
c
(HS
锛?
)<
c
(H
锛?
)
锛?脳10
锛?/p>
5
mol路L
锛?/p>
1
锛?/p>
A
椤归敊璇紱
B
椤癸紝
NH
3
路H
2
O
鏄急鐢佃В璐紝绋�閲婁績杩?/p>
NH
3
路H
2
O
鐨勭數绂伙紝鏁?/p>
a
<
b
锛?/p>
1
锛?/p>
B
椤归敊璇紱
C
椤癸紝娣峰悎婧舵恫涓瓨鍦ㄧ數鑽?
瀹堟亽锛?/p>
c
(Na
锛?/p>
)
锛?/p>
c
(H
锛?/p>
)
锛?/p>
c
(OH
锛?/p>
)
锛?/p>
c
(HC
2
O
锛?/p>
4
)
锛?/p>
2
c
(C
2
O
2
锛?
4
)
锛?/p>
C
椤归敊璇紱
D
椤癸紝鐢变簬閰告�?
CH
3
COOH>H
2
CO
3
>HClO
锛屾牴鎹�滆秺寮辫秺姘磋В鈥濈殑鍘熺悊鐭ワ紝姘磋В绋嬪害锛?/p>
ClO
锛?/p>
>HCO
锛?/p>
3
>CH
3
COO
锛?
锛屾墍浠?
pH
鐩稿悓鐨勪笁绉嶆憾娑蹭腑鐨?/p>
c
(Na
锛?
)
锛氣憼锛炩憽锛炩憿锛?/p>
D
椤规纭�?/p>
绛旀
D
2
锛?2016路璇炬爣鍏ㄥ浗鈪紝
13
锛?/p>
6
鍒?/p>
)
涓嬪垪鏈夊叧鐢佃В璐ㄦ憾娑茬殑璇存硶姝ｇ‘鐨勬槸
(
)
A
锛庡悜
0.1 mol路L
锛?/p>
1
CH
3
COOH
婧舵恫涓姞鍏ュ皯閲忔按锛屾憾娑蹭腑
c
锛?/p>
H
锛?/p>
锛?
c
锛?/p>
CH
3
COOH
锛?
鍑忓皬
B
锛庡皢
CH
3
COONa
婧舵恫浠?/p>
20 鈩冨崌娓╄嚦
30 鈩冿紝婧舵恫涓?/p>
c
锛?/p>
CH
3
COO
锛?/p>
锛?
c
锛?/p>
CH
3
COOH
锛壜?/p>
c
锛?/p>
OH
锛?/p>
锛?/p>
澧炲ぇ
C
锛庡悜鐩愰吀涓姞鍏ユ皑姘磋嚦涓�э紝婧舵恫涓?/p>
c
锛?/p>
NH
锛?/p>
4
锛?
c
锛?/p>
Cl
锛?/p>
锛?
>1
D
锛庡悜
AgCl
銆?/p>
AgBr
鐨勯ケ鍜屾憾娑蹭腑鍔犲叆灏戦噺
AgNO
3
锛屾憾娑蹭腑
c
锛?/p>
Cl
锛?/p>
锛?
c
锛?/p>
Br
锛?/p>
锛?
涓嶅彉
瑙ｆ瀽
A
椤癸紝
c
锛?/p>
H
锛?/p>
锛?/p>
c
锛?/p>
CH
3
COOH
锛?/p>
锛?/p>
K
a
c
锛?/p>
CH
3
COO
锛?/p>
锛?
锛屽姞姘寸█閲婏紝
c
(CH
3
COO
鈥?
)
鍑忓皬锛?/p>
K
a
涓嶅彉锛屾墍浠?
姣斿�煎澶э紝閿欒锛?/p>
B
椤癸紝
c
锛?/p>
CH
3
COO
锛?/p>
锛?/p>
c
锛?/p>
CH
3
COOH
锛壜?/p>
c
锛?/p>
OH
锛?
锛?/p>
锛?/p>
1
K
h
(
K
h
涓烘按瑙ｅ父鏁?/p>
)
锛屾俯搴﹀崌楂樻按瑙ｅ父鏁?/p>
K
h
澧炲ぇ锛屾瘮鍊煎噺灏忥紝閿欒锛?/p>
C
椤癸紝鍚戠洂閰镐腑鍔犲叆姘ㄦ按鑷充腑鎬э紝鏍规嵁鐢佃嵎瀹堟亽锛?/p>
c
(NH
锛?/p>
4
)
锛?/p>
c
(H
锛?
)
锛?/p>
c
(Cl
鈥?/p>
)
锛?/p>
c
(OH
鈥?/p>
)
锛屾鏃?/p>
c
(H
锛?/p>
)
锛?/p>
c
(OH
鈥?/p>
)
锛屾晠
c
(NH
锛?/p>
4
)
锛?/p>
c
(Cl
鈥?
)
锛屾墍浠?/p>
c
锛?/p>
NH
锛?/p>
4
锛?/p>
c
锛?/p>
Cl
锛?/p>
锛?
锛?/p>
1
锛岄敊璇紱
D
椤癸紝
鍦ㄩケ鍜屾憾娑蹭腑
c
锛?/p>
Cl
锛?/p>
锛?/p>
c
锛?/p>
Br
锛?/p>
锛?/p>
锛?/p>
K
sp
锛?/p>
AgCl
锛?/p>
K
sp
锛?/p>
AgBr
锛?/p>
锛?/p>
娓╁害涓嶅彉婧跺害绉?/p>
K
sp
涓嶅彉锛?/p>
鍒欐憾娑蹭腑
c
锛?/p>
Cl
锛?/p>
锛?
c
锛?/p>
Br
锛?/p>
锛?
涓?
鍙橈紝姝ｇ‘銆?/p>
绛旀
D
娌夋穩婧惰В骞宠