1
鍖椾含鍖栧伐澶у
2000
鑰冪爺鐗╃悊鍖栧璇曢
(
濉┖
16
鍒嗭紝閫夋嫨棰?/p>
9
鍒嗭紝璁＄畻
5
棰?/p>
75
鍒嗗叡
100
鍒?/p>
)
娉ㄦ剰浜嬮」锛氱瓟妗堝啓鍦ㄧ瓟棰樼焊涓婏紝
101.325kPa
鈮?/p>
100kPa=
p
锛屼綔鍥剧敤閾呯瑪銆?/p>
涓�銆佸～绌洪
(16
鍒?/p>
)
1. 1mol
鍙屽師瀛愮悊鎯虫皵浣撶敱濮嬫�?/p>
370K
銆?/p>
100kPa
鍒嗗埆缁?/p>
(1)
绛夊帇杩囩▼锛?/p>
缁?/p>
(2)
绛夊杩囩▼鍔犵儹鍒?/p>
473K
锛?/p>
鍒?/p>
(1)
锛?/p>
(2)
涓や釜杩囩▼涓嬪垪鐗╃悊閲忕殑鍏崇郴鏄?/p>
Q
1
_____Q
2
锛?/p>
W
1
_____W
2
锛屸柍
H
1
_____
鈻?/p>
H
2
锛屸柍
S
1
_____
鈻?/p>
S
2
銆?/p>
(
濉ぇ浜庛�?/p>
灏忎簬鎴栫瓑浜?/p>
)
2.
200
鈩冩椂锛?/p>
Ag
2
O
鐨勫垎瑙ｅ弽搴斾负锛?/p>
Ag
2
O(s)
鈫?/p>
2Ag(s)+
2
1
O
2
(g)
宸辩煡
200
鈩冩椂鍥轰綋
Ag
2
O
鐨勫垎瑙ｅ帇涓?/p>
137.8kPa
銆備粖璁?/p>
1mol
Ag
2
O(s)
鍦?/p>
200
鈩冨垎瑙ｈ揪骞宠 锛屽垯璇ヨ繃绋嬧柍
G=
_______
锛?/p>
K
=
_________
锛屽弽搴旇繃绋嬬郴缁熶笌鐜浜ゆ崲鐨勫姛
W=______(
蹇界暐鍥轰綋浣撶Н锛屽苟璁炬皵浣撲负鐞嗘兂
姘斾綋銆?/p>
3.
鏍规嵁鐢垫睜鍙嶅簲璁捐鍘熺數姹犮�傚繁鐭ョ數姹犲弽搴旓細
AgCl(s)+I
锛?
(
飥?/p>
I
a
)=AgI(s)+Cl
锛?
(
飥?/p>
Cl
a
)
鎵�璁捐鐨勫師鐢垫睜涓?/p>
__________________________________________
銆?/p>
4.
鏈夌悊鎯虫皵浣撳弽搴旓細
A(g)+2B(g)
鈫?/p>
C(g)
鍦ㄧ瓑娓╁拰鎬诲帇涓嶅彉鐨勬潯浠朵笅杩涜锛岃嫢鍘熸枡姘斾腑
A
涓?/p>
B
鐨勭墿璐ㄧ殑閲忎箣姣斾负
1:2
锛岃揪骞宠 鏃剁郴缁熺殑缁勫垎鏁?/p>
C=_______
锛岃嚜鐢卞害鏁?/p>
f=_______
銆傚綋娓╁害涓�瀹氭椂锛屽澶у帇鍔涘垯
K
_______(
濉澶с�佸噺灏忔垨涓嶅彉
)
锛屽钩琛?/p>
灏?/p>
________
绉诲姩
(
濉悜宸︺�佸悜鍙虫垨涓?/p>
)
銆?/p>
5.
鍦ㄤ竴涓敟褰㈠鍣ㄤ腑锛屾斁鍏ヤ竴婊存恫浣擄紝濡備笅鍥炬墍绀恒�傝瘯鐢诲嚭鎺ヨЕ瑙?/p>
胃
銆傚洜
胃
____90
0
(
濉ぇ浜庛�佸皬浜庢垨绛変簬
)
锛?
鍒欒娑蹭綋瀵瑰鍣?/p>
______
娑︽箍
(
濉兘鎴栦笉鑳?/p>
)
銆?/p>
6.
鏈?/p>
(N
銆?/p>
E
銆?/p>
V)
纭畾鐨勭悊鎯虫皵浣擄紝璁惧垎瀛愮殑杩愬姩褰㈠紡鍙湁涓変釜鍙強鐨勮兘绾э紝瀹冧滑鐨勮兘閲忓拰绠�骞跺害鍒嗗埆涓猴細
k
1
飦?/p>
=0K
锛?/p>
g
1
=1
k
2
飦?/p>
=100K
锛?/p>
g
1
=3
k
3
飦?/p>
=300K
锛?/p>
g
1
=5
(
寮忎腑
k
涓虹幓灏斿吂鏇煎父鏁?/p>
)
褰撴俯搴︿负
200K
鏃讹紝鍒嗗瓙鐨勯厤鍒嗗嚱鏁板�间负
_______
銆傚湪鏌愭俯搴︿笅锛岃嫢
kT
i
e
飦?/p>
飥?
鈫?/p>
1
鏃讹紝涓変釜鑳界骇涓婃渶鍙嚑鍒嗗瓙
鏁颁箣姣斾负
_____________
銆?/p>
(
娉細涓?/p>
i
飦?/p>
)
7.
璇疯璁″疄楠屾祴瀹氬弽搴?/p>
C
6
H
6
(l)+
2
15
O
2
鈫?/p>
6CO
2
(g)+3H
2
O(g)
鐨勬懇灏斿弽搴旂創鈻?/p>
r
H
m
銆傚疄楠屾柟娉曞強鐞嗚渚濇嵁鏄細
___________________________________
銆?/p>
(
涓嶈�冭檻鐢ㄥ厜
璋辨垨娉㈣氨鏂规硶锛屼笉瑕佹眰鍐欏嚭瀹為獙姝ラ鍜屽疄楠岃缃?/p>
)
銆?/p>
浜屻�侀�夋嫨棰?/p>
(9
鍒?/p>
)
1.
瀹為檯姘斾綋缁忚妭娴佽啫鑳�杩囩▼锛屾纭殑缁撹鏄細
[
]