绗?/p>
8
绔?/p>
閰嶄綅鍖栧悎鐗?/p>
銆?/p>
8-1
銆戝懡鍚嶄笅鍒楅厤鍚堢墿
锛?/p>
1
锛?/p>
K
2
[Ni(CN)
4
]
锛?/p>
2
锛?/p>
(NH
4
)
2
[FeCl
5
(H
2
O)]
锛?/p>
2
锛?/p>
[Ir(ONO)(NH
3
)
5
]Cl
2
锛?/p>
3
锛?/p>
Na
2
[Cr(CO)
5
]
瑙ｏ細
锛?/p>
1
锛夊洓姘板悎闀嶏紙
II
锛夐吀閽?/p>
锛?/p>
2
锛変簲姘?/p>
飪?/p>
涓�姘村悎閾侊紙
III
锛夐吀閾?/p>
锛?/p>
3
锛変簩姘寲浜氱閰告牴
飪?/p>
浜旀皑鍚堥摫锛?/p>
III
锛?/p>
锛?/p>
4
锛変簲缇板熀鍚堥摤锛?/p>
-II
锛夐吀閽?/p>
銆?/p>
8-2
銆戝啓鍑轰笅鍒楅厤鍚堢墿锛堥厤绂诲瓙锛夌殑鍖栧寮忥細
(1)
纭吀鍥涙皑鍚堥摐锛?/p>
II
锛?/p>
(2)
鍥涚～姘?/p>
飪?/p>
浜屾皑鍚堥摤锛?/p>
III
锛夐吀閾?/p>
(3)
浜岀緹鍩?/p>
飪?/p>
鍥涙按鍚堥摑锛?/p>
III
锛夌瀛?/p>
(4)
浜岃嫰鍚堥摤
瑙ｏ細
(1) [Cu(NH
3
)
4
]SO
4
(2) NH
4
[Cr(SCN)
4
(NH
3
)
2
]
(3) [Al(OH)
2
(H
2
O)
4
]
+
(4) Cr(C
6
H
6
)
2
銆?/p>
8-3
銆?/p>
AgNO
3
鑳戒粠
Pt(NH
3
)
6
Cl
4
婧舵恫涓皢鎵�鏈夌殑姘矇娣�涓?/p>
AgCl
锛屼絾鍦?/p>
Pt(NH
3
)
3
Cl
4
涓粎鑳芥矇娣�鍑?/p>
1/4
鐨勬隘锛岃瘯鏍规嵁杩欎簺浜嬪疄鍐欏嚭杩欎袱绉嶉厤鍚堢墿鐨勭粨鏋勫紡銆?/p>
瑙ｏ細鍓嶈�呬负
[Pt(NH
3
)
6
]Cl
4
锛屽悗鑰呬负
[PtCl
3
(NH
3
)
3
]Cl
銆?/p>
8-4
銆戠敾鍑轰笅鍒楅厤鍚堢墿鍙兘鏈夌殑鍑犲紓鏋勪綋锛?/p>
(1) [PtClBr(NH
3
)py]
锛堝钩闈㈡鏂瑰舰锛?/p>
(2) [Pt(NH
3
)
4
(NO
2
)Cl]Cl
2
(3) [Pt(NH
3
)
2
(OH)Cl
3
]
(4) [Pt(NH
3
)
2
(OH)
2
Cl
2
]
瑙ｏ細
锛?/p>
1
锛夋湁
3
绉嶅嚑浣曞紓鏋勪綋锛屽嵆鍦ㄦ隘绂诲瓙鐨勫浣嶅彲浠ュ垎鍒槸
Br
-
, NH
3
鎴?/p>
py
銆?/p>
锛?/p>
2
锛夊叚閰嶄綅搴斾负姝ｅ叓闈綋鏋勫瀷锛屾湁
2
绉嶅嚑浣曞紓鏋勪綋锛屽嵆姘瀛愭槸鍦ㄧ鍩虹殑瀵逛綅杩樻槸鍦ㄩ偦浣嶃�?/p>
锛?/p>
3
锛?/p>
鍏厤浣嶅簲涓烘鍏潰浣撴瀯鍨嬶紝
鏈?/p>
4
绉嶅嚑浣曞紓鏋勪綋锛?/p>
鍗虫皑鐨勫浣嶅垎鍒彲浠ユ槸姘ㄣ�?/p>
缇熷熀鍜屾隘绂诲瓙锛?/p>
褰撴皑鐨勫浣嶆槸姘瀛愭椂锛屽湪璧ら亾骞抽潰涓婂張鍙互鏈夊彟涓�涓皑鐨勫浣嶆槸缇熷熀鎴栨槸姘瀛愩�?/p>