瀹?/p>
楠屼竴锛?/p>
Co(
鈪?/p>
)Salen
锛介厤鍚堢墿鐨勫埗澶囧拰杞芥哀浣滅敤
瀹為獙鐩殑
1.
閫氳繃锛?/p>
Co(
鈪?/p>
)Salen
锛介厤鍚堢墿鐨勫埗澶囨帉鎻℃棤鏈哄悎鎴愪腑鐨勪竴浜涘熀鏈搷浣滄妧鏈紱
2.
閫氳繃锛?/p>
Co(
鈪?/p>
)Salen
锛介厤鍚堢墿鐨勫惛姘ч噺娴嬪畾鍜屾斁姘ц瀵熶簡瑙ｆ煇浜涢噾灞為厤鍚?/p>
鐗╃殑杞芥哀浣滅敤鏈哄埗銆?/p>
瀹為獙鍘熺悊
鍦ㄨ嚜鐒剁晫鐨勭敓鐗╀綋涓紝鏈夎澶氬惈鏈夎繃娓￠噾灞炵瀛愮殑铔嬬櫧锛屽叾涓湁浜涢噾灞炶泲鐧斤紝鍦ㄤ竴瀹氭潯浠朵笅锛?/p>
鑳藉鍚告敹鍜屾斁鍑烘哀姘旓紝浠ヤ緵鏈夋満浣撶敓鍛芥椿鍔ㄧ殑闇�瑕併�備緥濡傦紝鍚搧鐨勮倢绾㈣泲鐧姐�佽绾㈣泲鐧姐�佸惈閾?/p>
鐨勮娓呰泲鐧藉拰鍚拻鐨勮閽掕泲鐧界瓑銆傝繖浜涘ぉ鐒剁殑杞芥哀浣撶粨鏋勫鏉傦紝寰堟棭灏辫鍙戠幇銆傚湪涓�浜涙瘮杈冪畝
鍗曠殑鏃犳満閰嶅悎鐗╀腑涔熻瀵熷埌绫讳技鐨勭幇璞★紝杩欎簺绠�鍗曠殑鏃犳満鍚堢墿宸插箍娉涘湴琚綔鐢ㄧ爺绌惰浇姘т綋鐨勬ā
鎷熷寲鍚堢墿銆傚叾涓爺绌跺緱鏈�澶氱殑鏄挻鐨勯厤鍚堢墿銆傚鍙屾按鏉ㄧ缉涔欎簩鑳哄悎閽达蓟
Co(
鈪?/p>
)Salen
锛藉浘锛?/p>
5.1
锛?/p>
(5
OH
CHO
H
2
N
NH
2
+
2
OH
HC
HO
CH
N
N
O
HC
O
CH
N
N
Co
Co(CH
3
COO)
2
鍥?/p>
5.1
浠庨挻閰嶅悎鐗╃殑杞芥哀鍖栦綔鐢ㄧ爺绌朵腑鍙戠幇锛屽畠浠笌姘х殑缁撳悎鍙互鏈変袱绉嶄笉鍚岀殑绫诲瀷锛?/p>
鐢变簬閰嶄綋
L
鐨勬�ц川銆佸弽搴旀俯搴︺�佷娇鐢ㄦ憾鍓傜瓑鏉′欢鐨勪笉鍚岋紝
Co
涓?/p>
O
2
鐨勬懇灏旀暟姣斿彲浠ユ槸
1
鈭?/p>
1
鎴?/p>
2
鈭?/p>
1
銆?/p>
鏈疄楠屼互
[Co(
鈪?/p>
)Salen]
涓轰緥鏉ヨ娴嬮厤鍚堢墿鐨勫惛姘у拰鏀炬哀浣滅敤銆?/p>
[Co(
鈪?/p>
)Salen]
閰嶅悎鐗╃敱浜庡埗澶?/p>
鏉′欢鐨勪笉鍚屽彲浠ユ湁涓ょ涓嶅悓鐨勫浐浣撳舰鎬佸瓨鍦紙瑙佸浘
5.2
锛夛紝涓�绉嶆槸妫曡鑹茬矘鐘朵骇鐗?/p>
(
娲绘�у瀷
)
锛屽湪
瀹ゆ俯涓嬭兘杩呴�熷惛鏀舵哀姘旓紱鍙︿竴绉嶆槸鏆楃孩鑹叉櫠浣?/p>
(
闈炴椿鎬у瀷
)
锛屽湪瀹ゆ俯涓嬬ǔ瀹氾紝涓嶅惛鏀舵哀姘斻�?