璐ㄨ氨鍒嗘瀽涔犻
涓�銆佺畝绛旈
1
锛庝互鍗曡仛鐒﹁川璋变华涓轰緥锛岃鏄庣粍鎴愪华鍣ㄥ悇涓富瑕侀儴鍒嗙殑浣滅敤鍙婂師鐞嗐�?/p>
2
锛庡弻鑱氱劍璐ㄨ氨浠负浠�涔堣兘鎻愰珮浠櫒鐨勫垎杈ㄧ巼
3
锛庤瘯杩伴琛屾椂闂磋川璋辫鐨勫伐浣滃師鐞?/p>
,
瀹冩湁浠�涔堢壒鐐?/p>
4
锛庢瘮杈冪數瀛愯桨鍑荤瀛愭簮銆佸満鑷寸數绂绘簮鍙婂満瑙ｆ瀽鐢电婧愮殑鐗圭偣銆?/p>
5
锛庤瘯杩板寲瀛︾數绂绘簮鐨勫伐浣滃師鐞嗐�?/p>
6
锛?/p>
鏈夋満鍖栧悎鐗╁湪鐢靛瓙杞板嚮绂诲瓙婧愪腑鏈夊彲鑳戒骇鐢熷摢浜涚被鍨嬬殑绂诲瓙浠庤繖浜涚瀛愮殑璐ㄨ氨宄颁腑鍙互寰楀埌涓�浜涗粈涔堜俊
鎭?/p>
7
锛庡浣曞埄鐢ㄨ川璋变俊鎭潵鍒ゆ柇鍖栧悎鐗╃殑鐩稿鍒嗗瓙璐ㄩ噺鍒ゆ柇鍒嗗瓙寮?/p>
8
锛庤壊璋变笌璐ㄨ氨鑱旂敤鍚庢湁浠�涔堢獊鍑虹壒鐐?/p>
9
锛庡浣曞疄鐜版皵鐩歌壊璋憋紞璐ㄨ氨鑱旂敤
10
锛庤瘯杩版恫鐩歌壊璋憋紞璐ㄨ氨鑱旂敤鐨勮揩鍒囨�с�?/p>
浜屻�侀�夋嫨棰?/p>
1
锛?/p>
3,3-
浜岀敳鍩烘垔鐑凤細
鍙楀埌鐢靛瓙娴佽桨鍑诲悗
,
鏈�瀹规槗鏂鐨勯敭浣嶆槸
:
(
)
A
1
鍜?/p>
4
B
2
鍜?/p>
3
C
5
鍜?/p>
6
D
2
鍜?/p>
3
2
锛庡湪涓佺兎鐨勮川璋卞浘涓紝
M
瀵?/p>
(
M
锛?/p>
1)
鐨勬瘮渚嬫槸
锛?/p>
锛?/p>
A
100:
B
100:
C
100:
D
100:
3
锛庝笅鍒楀寲鍚堢墿鍚?/p>
C
銆?/p>
H
鎴?/p>
O
銆?/p>
N
锛岃瘯鎸囧嚭鍝竴绉嶅寲鍚堢墿鐨勫垎瀛愮瀛愬嘲涓哄鏁?/p>
(
)
A
C
6
H
6
B
C
6
H
5
NO
2
C
C
4
H
2
N
6
O D
C
9
H
10
O
2
4
锛庡湪涓嬪垪鍖栧悎鐗╀腑
,
浣曡�呬笉鑳藉彂鐢熼害姘忛噸鎺?/p>
(
)
5
锛庣敤璐ㄨ氨娉曞垎鏋愭棤鏈烘潗鏂欐椂锛屽疁閲囩敤涓嬭堪鍝竴绉嶆垨鍑犵鐢电婧?/p>
锛?/p>
锛?/p>
A
鍖栧鐢电婧?/p>
B
鐢靛瓙杞板嚮婧?/p>
C
楂橀鐏姳婧?/p>
D
B
鎴?/p>
C
6
锛庢煇鍖栧悎鐗╃殑璐ㄨ氨鍥句笂鍑虹幇
m
/
z
31
鐨勫己宄?/p>
,
鍒欒鍖栧悎鐗╀笉鍙兘涓?/p>
(
)
A
閱?/p>
B
閱?/p>
C
鑳?/p>
D
閱氭垨閱?/p>
7
锛庝竴绉嶉叝绫伙紙
M
=116
锛夛紝璐ㄨ氨鍥句笂鍦?/p>
m
/
z
57
锛?/p>
100%
锛夛紝
m
/
z
29
锛?/p>
27%
锛夊強
m
/
z
43
锛?/p>
27%
锛夊鍧囨湁绂诲瓙宄帮紝
鍒濇鎺ㄦ祴鍏跺彲鑳界粨鏋勫涓嬶紝璇曢棶璇ュ寲鍚堢墿缁撴瀯涓?/p>
(
)
A
(CH
3
)
2
CHCOOC
2
H
5
B
CH
3
CH
2
COOCH
2
CH
2
CH
3
C
CH
3
(CH
2
)
3
COOCH
3
D
CH
3
COO(CH
2
)
3
CH
3
8
锛庢寜鍒嗗瓙绂诲瓙鐨勭ǔ瀹氭�ф帓鍒椾笅闈㈢殑鍖栧悎鐗╂搴忓簲涓?/p>
(
)
A
鑻?/p>
>
鍏辫江鐑儍
>
閰?/p>
>
閱?/p>
B
鑻?/p>
>
閰?/p>
>
鍏辫江鐑儍
>
閱?/p>
C
鍏辫江鐑儍
>
鑻?/p>
>
閰?/p>
>
閱?/p>
D
鑻?/p>
>
鍏辫江鐑儍
>
閱?/p>
>
閰?/p>
9
锛庡寲鍚堢墿
鍦ㄨ川璋卞浘涓婂嚭鐜扮殑涓昏寮哄嘲鏄?/p>
锛?/p>
锛?/p>
A
m/z
15
B
m/z
29
C
m/z
43
D
m/z
71
10
锛庢捍宸辩兎缁?/p>
鍧囪鍚庯紝鍙骇鐢熺殑绂诲瓙宄扮殑鏈�鍙兘鎯呭喌涓猴細
(
)
A
m
/
z
93
B
m
/
z
93
鍜?/p>
m
/
z
95
C
m
/
z
71
D
m
/
z
71
鍜?/p>
m
/
z
73
11
锛庡湪
C
2
H
5
F
涓紝
F
瀵逛笅杩扮瀛愬嘲鏈夎础鐚殑鏄?/p>
(
)
A
M
B
M
+1
C
M
+2
D
M
鍙?/p>
M
+2
12
锛庢煇鍖栧悎鐗╃殑
M
S
鍥句笂鍑虹幇
m
/
e
74
鐨勫己宄帮紝
R
鍏夎氨鍦?/p>
3400
锝?/p>
3200c
m
-1
鏈変竴瀹藉嘲锛?/p>
1700
锝?/p>
1750c
m
-1
鏈変竴寮哄嘲锛屽垯璇ュ寲鍚堢墿鍙兘鏄?/p>
锛?/p>
锛?/p>
A
R
1
锛嶏紙
CH
2
锛?/p>
3
锛?/p>
COOCH
3
B
R
1
锛嶏紙
CH
2
锛?/p>
4
锛?/p>
COOH
C
R
1
锛?/p>
CH
2
(CH
3
)
锛?/p>
CH
2
锛?/p>
CH
锛?/p>
COOH
D
B
鎴?/p>
C
13
锛庡湪璐ㄨ氨鍥捐氨涓嫢鏌愮儍鍖栧悎鐗╃殑
(M
锛?/p>
1)
鍜?/p>
M
宄扮殑寮哄害姣斾负
24: 100
锛屽垯鍦ㄨ鐑冧腑瀛樺湪纰冲師瀛愮殑涓暟涓?/p>
锛?/p>
锛夈�?/p>
A
2
B
8
C
22
D
46