2014
骞村垎鏋愬寲瀛﹁鍚庝綔涓氬弬鑰冪瓟妗?/p>
P25
锛?/p>
1
锛庢寚鍑哄湪涓嬪垪鎯呭喌涓嬶紝鍚勪細寮曡捣鍝璇樊锛熷鏋滄槸绯荤粺璇樊锛屽簲璇ラ噰鐢ㄤ粈涔堟柟娉曞噺鍏嶏紵
锛?/p>
1
锛?/p>
鐮濈爜琚厫铓�锛?/p>
锛?/p>
2
锛?/p>
澶╁钩鐨勪袱鑷備笉绛夐暱锛?/p>
锛?/p>
3
锛?/p>
瀹归噺鐡跺拰绉绘恫绠′笉閰嶅锛?/p>
锛?/p>
4
锛?/p>
璇曞墏涓惈鏈夊井閲忕殑琚祴缁勫垎锛?/p>
锛?/p>
5
锛?/p>
澶╁钩鐨勯浂鐐规湁寰皬鍙樺姩锛?/p>
锛?/p>
6
锛?/p>
璇诲彇婊村畾浣撶Н鏃舵渶鍚庝竴浣嶆暟瀛椾及璁′笉鍑嗭紱
锛?/p>
7
锛?/p>
婊村畾鏃朵笉鎱庝粠閿ュ舰鐡朵腑婧呭嚭涓�婊存憾娑诧紱
锛?/p>
8
锛?/p>
鏍囧畾
HCl
婧舵恫鐢ㄧ殑
NaOH
鏍囧噯婧舵恫涓惛鏀朵簡
CO
2
銆?/p>
绛?/p>
:
锛?/p>
1
锛夌郴缁熻宸腑鐨勪华鍣ㄨ宸�傚噺鍏嶇殑鏂规硶锛氭牎鍑嗕华鍣ㄦ垨鏇存崲浠櫒銆?/p>
锛?/p>
2
锛夌郴缁熻宸腑鐨勪华鍣ㄨ宸�傚噺鍏嶇殑鏂规硶锛氭牎鍑嗕华鍣ㄦ垨鏇存崲浠櫒銆?/p>
锛?/p>
3
锛夌郴缁熻宸腑鐨勪华鍣ㄨ宸�傚噺鍏嶇殑鏂规硶锛氭牎鍑嗕华鍣ㄦ垨鏇存崲浠櫒銆?/p>
锛?/p>
4
锛夌郴缁熻宸腑鐨勮瘯鍓傝宸�傚噺鍏嶇殑鏂规硶锛氬仛绌虹櫧瀹為獙銆?/p>
锛?/p>
5
锛夐殢鏈鸿宸�傚噺鍏嶇殑鏂规硶锛氬璇诲嚑娆″彇骞冲潎鍊笺�?/p>
锛?/p>
6
锛夐殢鏈鸿宸�傚噺鍏嶇殑鏂规硶锛氬璇诲嚑娆″彇骞冲潎鍊笺�?/p>
锛?/p>
7
锛夎繃澶辫宸�?/p>
锛?/p>
8
锛夌郴缁熻宸腑鐨勮瘯鍓傝宸�傚噺鍏嶇殑鏂规硶锛氬仛绌虹櫧瀹為獙銆?/p>
3
锛庢淮瀹氱鐨勮鏁拌宸负
卤
0.02mL
銆傚鏋滄淮瀹氫腑鐢ㄥ幓鏍囧噯婧舵恫鐨勪綋绉垎鍒负
2mL
鍜?/p>
20mL
宸?/p>
鍙筹紝璇绘暟鐨勭浉瀵硅宸悇鏄灏戯紵浠庣浉瀵硅宸殑澶у皬璇存槑浜嗕粈涔堥棶棰橈紵
瑙ｏ細鍥犳淮瀹氱鐨勮鏁拌宸负
0.02mL
锛屾晠璇绘暟鐨勭粷瀵硅宸?/p>
a
0.02
m
L
a
鏍规嵁
r
100%
鍙緱
r
0.2
m
L
2
mL
mL
2
100%
1%
r
0.
0
2mL
20
mL
mL
20
100%
0.1%
杩欒鏄庯紝閲忓彇涓ゆ憾娑茬殑缁濆璇樊鐩哥瓑锛屼絾浠栦滑鐨勭浉瀵硅宸苟涓嶇浉鍚屻�備篃灏辨槸璇达紝褰?/p>
琚祴瀹氱殑閲忚緝澶ф椂锛屾祴閲忕殑鐩稿璇樊杈冨皬锛屾祴瀹氱殑鍑嗙‘绋嬪害涔熷氨杈冮珮銆?/p>
4
锛庝笅鍒楁暟鎹悇鍖呮嫭浜嗗嚑浣嶆湁鏁堟暟瀛楋紵
-5
锛?/p>
1
锛?/p>
0.0330
(2) 10.030
(3) 0.01020
(4) 8.7
脳
10
(
5) pKa=4.74
(6) pH=10.00
绛旓細锛?/p>
1
锛変笁浣嶆湁鏁堟暟瀛?/p>
锛?/p>
2
锛変簲浣嶆湁鏁堟暟瀛?/p>
锛?/p>
3
锛夊洓浣嶆湁鏁堟暟瀛?/p>
锛?/p>
4
锛?/p>
涓や綅鏈夋晥鏁板瓧
锛?/p>
5
锛?/p>
涓や綅鏈夋晥鏁板瓧
锛?/p>
6
锛変袱浣嶆湁鏁堟暟瀛?/p>
-1
9
锛庢爣瀹氭祿搴︾害涓?/p>
0.1mol
路
L
鐨?/p>
NaOH
锛屾娑堣�?/p>
NaOH
婧舵恫
20mL
宸﹀彸锛屽簲绉板彇鍩哄噯鐗╄川
H
2
C
2
O
4
路
2H
2
O
澶氬皯鍏嬶紵鍏剁О閲忕殑鐩稿璇樊鑳藉惁杈惧埌
0.
1%
锛熻嫢涓嶈兘锛屽彲浠ョ敤浠�涔堟柟娉曚簣浠?/p>
鏀瑰杽锛熻嫢鏀圭敤閭昏嫰浜岀敳閰告阿閽句负鍩哄噯鐗╋紝缁撴灉鍙堝浣曪紵
瑙ｏ細鏍规嵁鏂圭▼
2NaOH+H
2
C
2
O
4
路
H
2
O==Na
2
C
2
O
4
+3H
2
O
鍙煡锛?/p>
闇�
H
2
C
2
O
4
路
H
2
O
鐨勮川閲?/p>
m
1
涓猴細
0.1
0.020
m
126.07
0.13g
1
2